Fast and Scalable Printing of Large Area Monolayer Nanoparticles for Nanotexturing Applications-材料合成化学课件PPT.pptVIP

Fast and Scalable Printing of Large Area Monolayer Nanoparticles for Nanotexturing Applications nanotexturing Nanotexturing a substrate is an important means to enhance many physical and chemical functions nanowires Nanocone nanodome nanopillar Eg : highly ordered nanoscale texturing can dramatically increase light absorption in thin-?lm solar cells methods —produce nanotextured surfaces electron-beam lithography vapor liquid solid growth Langmuir Blodgett deposition spin coating dip coating Until now These methods are useful for fundamental studies but are not easily scaled to large areas with fast and low-cost processing. processes parameters applications Fast and Scalable Printing of Large Area Monolayer Nanoparticles A method based on the wire-wound rod coating method The wire-wound rod coating method: Deposits an even amount of ?uid over a moving surface and is used to manufacture of?ce products and ?exible packaging. Fast and Scalable Printing of Large Area Monolayer Nanoparticles——processes Silica nanoparticles: synthesized by a modi?ed St?ber process. A silica nanoparticle ink: prepared by mixing the nanoparticles with poly-4-vinylphenol (PVPh) in ethanol. The coating assembly consisted of a wire-wound rod, which is a stainless steel rod with stainless steel wire wound around it. stainless steel Processes:The nanoparticle ink was dropped onto the substrate and the rod was pulled across, leaving behind a volume of solution equal to the groove space between each wire winding and ultimately leading to a uniform ?lm。 Flexible substrate——PET (b) An optical image of a close-packed silica nanoparticle monolayer printed by the wire-wound rod coating method on a ?exible poly(ethylene terephtha- late) (PET) substrate. Four insets show SEM images of the monolayer on different spots. Parameters Since the assembly process occurs during the drying step, several parameters play a critical role in achieving close-packed nanoparticle arrays over large areas