Nanoparticle-polymer photovoltaic cells-材料合成化学课件PPT.pptVIP

Nanoparticle-polymer photovoltaic cells Introduction Conventional solar cells the efficiency is high(24%) expensive inorganic materials(Si) energy intensive processing techniques Nanoparticle-polymer photovoltaic(PV) cells inexpensive, easily processable functionality can be tailored by molecular desigen and chemical synthesis good PCE(31%,10%) organic nanoparticle-polymer PV cells hybrid inorganic nanoparticle-polymer PV cells two types General principle External quantum efficiency(EQE) The PCE for a cells generally increases with the EQE. A high EQE dose not necessarily guarantee a high PCE Dispersetion semiconducting nanoparticle within the polymer phase to give bulk heterojunction(BHJ)(b),the average polymer phase domain size is less than Lex and the much greater area of the acceptor/donor interface. External quantum efficiency(EQE) Nanoparticle used in the photoactive layer A key part of the assemble of nanoparticle-polymer PV cells is formation of a photoactive layer using nanoparticles dispersed in a polymer solution. Organic nanoparticles commonly used in nanoparticle-polymer PV cells are PCBM,PC71BM and SWNT. Polymersused in the photoactive layer The photoactive layers for the PCBM-P3HT PV cells give thhe higtest PCE values. Fabrication of P3HT/PCBM CORE material exists as rigid rod Not possible for Electrospinning PEO added Increases the viscosity and spinnability P3HT SHELL material P3HT (Mn=45 000–65 000) PCBM chloroform/toluene (3.5/1 wt.-%) PVP 10 wt.-% ( Mn=1 300 000) chloroform/ethanol (1/1 wt.-%) *Fabrication of P3HT/PCBM solar cloth by electrospinning technique, Subramanian Sundarrajan, Materials Letters Schematic diagram of core-shell electrospinning DC voltage at 18 KV; P3HT/PCBM flow rate is 1.3 mL/h; PVP flow rate is 0.8 mL/h; Room temperature with relative humidity of 50–60 %. 参数 Structural Characterization Length： several μm Diameters: 0.90 ~ 1.5 μm 1.2 μm average Contras