石墨精制废水中氟离子浓度测定偏差问题的解析.PDF

第 50 卷 第x 期 Vol.50 No.x 哈 尔 滨 工 业 大 学 学 报 2 0 1 8 年x月 2018 JOURNAL OF HARBIN INSTITUTE OF TECHNOLOGY DOI:10.11918/j.issn.0367-6234.201706020 石墨精制废水中氟离子浓度测定偏差问题的解析 高学睿，郑 彤，王 鹏 （哈尔滨工业大学环境学院，哈尔滨 150090 ） 摘要：随着高纯石墨日益成为现代科技与工业发展的重要原料，石墨精制产生的酸性含氟废水量也会越来 越大，其处理结果监测的准确性对控制该行业的环境冲击有着重要作用。实验中发现了氟离子选择电极法 测定石墨精制废水沉淀处理出水时，测量结果随水样稀释倍数增加而增高的问题。本文通过水质分析和理 论计算对可能存在的氟化钙微晶稀释溶解、离子强度波动、共存离子干扰等因素进行了排查，并用离子色 谱法对测量结果进行了核对。结果表明：稀释液中过量的掩蔽剂TISAB将溶液中络合态的氟离子释放出来， 是导致离子选择电极法氟离子浓度测定结果随稀释倍数增加而增高的主要原因；石墨精制废水处理出水中 氟离子浓度约在0至30mg/L 之间，用国家标准方法对其氟离子浓度测定需先将水样稀释100倍。 关键词：石墨精制废水;氟离子;氟离子选择电极;稀释;含氟络合物 中图分类号：X522 Analysis of measurement deviation problem of fluoride ion concentration in graphite refining wastewater GAO Xuerui,ZHENG Tong ，WANG Peng (Harbin Institute of Technology, Department of Environment, Harbin 150090) Abstract: With high purity graphite has become an important raw material of modern science,technology and industrial development, more and more fluoride-containing wastewater will be produced.The accurate monitor plays an important role in the control of the industrys environmental impact.It is found that fluorine ion concentration measured by fluoride ion selective electrode increased with the increasing of dilution ratio when measured graphite refining wastewater.Reasons like dissolution of suspended calcium fluoride micro-crystal, the interference of impurity ions and the effect of ionic strength were analyzed through water quality analysis and theoretical calculation. Ion