生活垃圾填埋场渗滤液性质随时间变化关系研究.docVIP

生活垃圾填埋场渗滤液性质随时间变化关系研究 楼紫阳，赵由才，李雄，刘振宇 同济大学污染控制与资源化研究国家重点实验室，上海20092 摘要： 对上海老港填埋场不同年份渗滤液取样，测定了以下参数：电导率、ORP、CODCr、NPOC、NH3-N、TN、正磷酸盐与总磷、pH、阴离子（F-、Cl-、Br-、SO42-），并建立了各参数与时间的关系。发现不同渗滤液指标随填埋时间延长，其变化趋势略有差异，其中NPOC、COD、N、P、pH、电导率等指标值随时间的延长，总体表现为降低趋势；而ORP则逐渐升高；阴离子等变化趋势不明显，呈现波动趋势。对于相同变化趋势的指标，其降解过程也并不一致，对于含C物质－NPOC和COD，经年降解后分别达到500 mgL-1 和2000 mgL-1；对于含N物质，则可分为三个阶段，前年的快速降解阶段，随后年的中速降解，最后进入慢速降解阶段稳定在500 mgL-1以内；TP含量随填埋时间在开始的年内降解迅速，从35 mgL-1降到3.4 mgL-1，后基本维持稳定值；pH值则在开始的年内下降较快，随后变化不大；电导率在填埋开始的7年内下降较快；而ORP则在开始的9年内上升较多。同时发现，随着填埋时间的延长，NPOC/TOC、NH3-N/TN、正磷酸盐/TP比例总体表现为降低，硫酸根/Cl-比例有稍微升高，最终保持在0.2左右。 关键词： 渗滤液， 老港填埋场，不同时间，性质表征 Characteristics of leachate with different ages from Laogang Refuse Landfill Lou Ziyang Zhao Youcai Song Yu Li Xiong LiuZhengyu The State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092 Abstract: Leachate with different ages were collected from Laogang Landfill in Shanghai, China, and the parameters, such as conductivity、ORP、CODCr、NPOC、NH3-N、TN、orthophosphate、TP、pH、 anion ions (F-、Cl-、Br-、SO42-), were determined, and the relationship between the parameters and times were co-related. It is found that values of these parameters, such as NPOC、COD、N、P、pH、conductivity, generally decreased and ORP increased and anions fluctuated, as time extended. NPOC and COD decreased quickly in the first 4 years to 500 mg?L-1 and 2000 mg?L-1, respectively. The decomposition process of N can be divided into three stages, i.e., degradation fastest in the first 4 years, and then degradation slow in the next 3 years, while slower degradation in the latter 6 years, which reached to below 500 mg?L-1. TP decreased quickly in the first 9 years, and then reached to a stable value of around 3.4 mg?L-1. pH declined slightly in the first 7 years, and then almost reached to a stable value of around 7.5. For conductivity, it decreased fast in the initial 7 years after landfill while ORP increased remarkably in the first 9 years. It is also found