层间化学反应组装.ppt

Claudia Haensch,aStephanie Hoeppener*band Ulrich S. Schubert Chem.Soc.Rev.,2010,39, 2323–2334 | 2323 Abstract Abstract Contents 1.Introduction 1.Introduction 1.Introduction 2.Surface modification of solid substrates 2.Surface modification of solid substrates 2.Surface modification of solid substrates 2.Surface modification of solid substrates 2.Surface modification of solid substrates 2.Surface modification of solid substrates 2.1 Nucleophilic substitution 2.1 Nucleophilic substitution 2.1 Nucleophilic substitution 2.1 Nucleophilic substitution Diagram 2.2 Click chemistry 2.2 Click chemistry 2.2 Click chemistry 2.2 Click chemistry Diagram Diagram 2.3 Supramolecular modification 2.3 Supramolecular modification 2.3 Supramolecular modification 2.3 Supramolecular modification 3. Conclusions * L O G O * L o g o Chemical modification of self -assembled silane based monolayers by surface reactions we look at how the functionalization of solid substrates by self-assembly processes provides the possibility to tailor their surface properties in a controllable fashion. One class of molecules, which attracted significant attention during the past decades, are silanes self assembled on hydroxyl terminated substrates,e.g.silicon and glass.The introduction of chemical functionalities in such monolayers can be generally obtained via two methods. This involves either the use of pre-functionalized molecules, which can be synthesized by different synthetic routes and subsequent self-assembly of these moieties on the surface. The second method utilizes chemical surface reactions for the modification of the monolayer. The following review highlights a selection of chemical surface reactions,i.e., nucleophilic substitution, click chemistry and supramolecular modification, which have been used for the functionalization of solid substrates . 1 2 3 Introduction Surface modification of solid substrates Conclusions The following review focuses on the chemical modi