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graphene_oxide氧化石墨烯

APPLIED PHYSICS LETTERS 92, 263302 2008 Organic solar cells with solution-processed graphene transparent electrodes Junbo Wu,1 Héctor A. Becerril,2 Zhenan Bao,2 Zunfeng Liu,3 Yongsheng Chen,3 and Peter Peumans4,a 1 Department of Materials Science and Engineering, Stanford University, Stanford, California 94305, USA 2 Department of Chemical Engineering, Stanford University, Stanford, California 94305, USA 3 Key Laboratory for Functional Polymer Materials and Center for Nanoscale Science and Technology, College of Chemistry, Institute of Polymer Chemistry, Nankai University, Tianjin 300071, People’s Republic of China 4 Department of Electrical Engineering, Stanford University, Stanford, California 94305, USA Received 22 January 2008; accepted 25 March 2008; published online 1 July 2008 We demonstrate that solution-processed graphene thin films can serve as transparent conductive anodes for organic photovoltaic cells. The graphene electrodes were deposited on quartz substrates by spin coating of an aqueous dispersion of functionalized graphene, followed by a reduction process to reduce the sheet resistance. Small molecular weight organic solar cells can be directly deposited on such graphene anodes. The short-circuit current and fill factor of these devices on graphene are lower than those of control device on indium tin oxide due to the higher sheet resistance of the graphene films. We anticipate that further optimization of the reduction conditions will improve the

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