草净津合成(英文).pdfVIP

Fresenius J Anal Chem (1998) 360 : 679–682 © Springer-Verlag 1998 ORIGINAL PAPER W. Zwickenpflug · H. Weiß · N. Fürst-Hunnius · E. Richter Separation of the reaction products of cyanazine and terbuthylazine nitrosation by thin-layer chromatography Received: 25 August 1997 / Revised: 13 October 1997 / Accepted: 21 October 1997 Abstract N-Nitroso-triazine herbicide species were syn- total, including metabolites [2]. Therefore high analytical thesized as reference standards and their reaction products quality on separation and detection techniques are neces- were separated by TLC. The method was established for sary and only some high performance liquid chroma- analytical as well as for preparative amounts to achieve a graphic, gas chromatographic and high performance thin- sufficient separation between the educts, the byproducts layer chromatographic (HPLC, GC and HPTLC) proce- and the N-nitrosated moieties. Separation of the reaction dures are officially approved for drinking water screening mixture was performed by two-dimensional TLC, using methods. For analysis of s-triazine herbicides in water the different mobile phases for each dimension. In the second compounds themselves and their degradation products, dimension two developments were executed using the hydroxylated, carboxylated, and N-dealkylated deriva- same solvent mixture. To examine the quality of perfor- tives, represent the analytically relevant species. In the mance, the separation zones were scrapped off, extracted case of HPTLC chromatography the automated multiple and analyzed in the HPLC-diode array detection (DAD) development method (AMD-