无机及分析化学第六章课后习题答案(高等教育出版社,第二版)69167推荐.pptVIP

* * (－)Pt∣Fe 2+（C1）,Fe 3+(C2)‖MnO4-(C3),Mn2+(C4)∣Pt (＋) E? ＝ 1.51V-0.771V=0.739V 3) E＝ ?(+)－?(-)＝ ?(+)?＋ - ?(-)? =1.51V+0.0592/5 lg108 –0.771V =0.83V * 6-10, E＝ E(+)－E(-)＝1.51V [E(Ag+/Ag)?+0.0592V lg(Ag+)]-E(Zn2+/Zn)?+ 0.0592V lg(Zn2+)] =1.51V 由于C(Ag+)=0.10 mol/L 所以 C(Zn2+)=0.57 mol/L * 6-11 查表， E(Sn2+/Sn)?=-0.136V, E(Pb2+/Pb)?=-0.126V 因为， E? ＝ E(+)? －E(-)? 0.22V=-0.136V- E(-)? E(-)? = E(PbSO4/Pb)? =-0.356V= E(PbSO4/Pb)= E(Pb2+/Pb)?+ 0.0592/2 lgC(Pb2+) = -0.126V + 0.0592/2 lgK?SP (PbSO4)/C(SO42-) lgK?SP (Pb