新型铝电解惰性阳极材料研究进展及展望刘英12王卫2刘英女.DOCVIP

新型铝电解惰性阳极材料研究进展及展望 刘 英1,2 王卫2 刘英：女，1987年生，博士生王卫：男，1985年生，工程师 通讯作者：刘英，通讯地址：河南省郑州市上街区安阳路中铝科技孵化园 ） 摘要：惰性阳极材料的研发一直是制约现代铝电解工业革命的关键技术, 本论文综述了近年来取得显著进展的两种惰性阳极材料体系：铁酸镍基金属陶瓷惰性阳极材料和合金阳极材料体系。以铁酸镍尖晶石为基础的金属陶瓷惰性阳极材料具有优越的抗腐蚀性能, 但其工业化面临的问题相对较多。合金阳极具有优良的导电性和力学性能, 适于加工成型和制备复杂形状, 但耐高温熔盐腐蚀性能差。惰性阳极与可湿润性阴极的综合应用, 结合低温铝电解技术的发展, 必将加快铝工业革命的步伐, 促进铝电解工业的绿色可持续发展。 关键词： 铝电解, 惰性阳极, 综述, 金属陶瓷, 合金阳极 分类号： 文章编号： Research development and prospects of inert anode materials for aluminium electrolysis Liu Ying1,2 Wang Wei2 (1.General Research Institute for Nonferrous Metals, Beijing 100088; Zhengzhou Non-ferrous Metals Research Institute Co.Ltd of CHALCO, Zhengzhou 450041) To whom correspondence should be addressed, Tel: 0371 E-mail: 371468939@163.com Abstract: The revolution for modern aluminium industrial is restricted by the key technology of the development for inert anode using in aluminum electrolysis. This paper reviewed two significant progressed inert anode material: the cermet inert anode with ferrite nickel and alloy anode. It has been paid much attention to the ferrite nickel based cermet inert anode material due to its superior corrosion resistance. Nevertheless, there are still lots of problems for its industrialization application. Alloy anode has excellent electrical conductivity and mechanical properties, which are also suitable for molding, processing and preparation into complex shapes. But the high temperature corrosion resistance in molten salt is poor for alloy anode. Combined with wettable cathode and low-temperature aluminum electrolysis technology, inert anode technology is bound to accelerate the pace of aluminum industrial revolution, which will promote the sustainable development for aluminum electrolysis. Keywords: aluminium electrolysis, inert anode, review, cermet, alloy anode 中国铝业股份有限公司重大科技专项：高效绿色铝电解工艺技术研发； 项目编号：ZY2009CBBB02 自1886年美国霍尔（C.M.Hall）和法国埃鲁特（P.L.T. Héroult）同时用冰晶石-氧化铝熔盐电解法制取金属铝之后, 霍尔-埃鲁特法便成为近现铝电解工业唯一的炼铝方法。此方法普遍使用可消耗的炭素材料作为阳极, 电解反应为2Al2O3