中国沉积盆地中流体-岩石相互作用.docVIP

中国沉积盆地中流体-岩石相互作用 第22卷第2期 2005年3月 中国科学院研究生院 JournaloftheGraduateSchooloftheChineseAcademyofSciences Vo1.22No.2 March2Oo5 Articlem:1002.I175(2oo5)o2.0239-09 EXCERIyIOFDISSERTATION Fluid.RockInteractioninChinese SedimentaryBasins CAIChun—FangWANGJi—YangGUJia—Yu (1Ins~uteofGeologyandGeophysics,ChineseAcademyofSdences,成100029,Ch/na; 2InstituteofPetroleumExplorationandDevdopment,PetroChioa,Be/ring100083,Ch/na) (Received16June2oo4) CsiCF.Wang.Gu.Fluid-RockInteractioninChineseSedimentaryBasins ChineseAcademySciences,2005,22(2):239—247 AbstractThepapersummarizesourrecentworkinfluid-rockinteractioninsedimentarybasinsin China.Weshowsomeresultsofexperimentstodissolvemicrocline,addressoriginandevolutionof oilfieldwaterintermsofstableisotopiccompositionandchemicaldata,andpresentcasestoshow thermochemicalsulfatereduction(TSR)andbacterialsulfatereduction(BSR)intheSichuanbasin, OrdosbasinandTarimbasin.Thestudyimpliesthatwater-rockinteractionandorganic-inorganic reactionsinoilandnaturalgasreservoirsareverycommonprocesseswhicharenotfullyrealized presently. Keywordsorganic-inorganicreaction,formationwater,sulfurisotope,boronisotope CLCP61.P59 1Introduction Huid-rockinteractioninsedimentarybasinsisrelatedtopetroleumgeneration,migration,accumulationand preservation,andisatopicofgeologicalfrontier.Wandothercoworkersbeganstudyingmicrobe-andorganic matter-mediatedfluid.rockinteractionin1991,whichWasunprecedentedinChina.Sincethen,alotofsignificant progresseshavebeenmade.Themethodswehavebeenusingaletointegrateanalysesonchemistryandisotopic composition(6C,8D,6伸O,S,6N,6¨Band盯Sr/86Sr)ofoil,gas,waterandmineralsin联呛mirrock, andexperimentalsimulationandchemicalthermodynamicsmodelingusingsoftwarecodessuchasSOLMINEQ.88…. Usingthemethods,weCalltracemineraldissolutionandprecipitation,discussorigin,evolution,secondary alterationandflowpathwaysofthefluids,deducechemicalreactions,partofwhichmayhaveoccurredinnaturebut presentlynotrecurredsuccessivelyunderlaboratoryconditions,andelucidatetheirisotopefractio