利用剩余活性污泥生产一次性可降解材料.doc

拟再审修改稿，稿件编号：201104032 利用剩余活性污泥生产一次性可降解材料 庞旭1 , 胡文锋1* , 蔡宏2 , 欧阳友生3 , 施庆珊3 , 张长勇1 , 疏秀林3 1华南农业大学食品学院生物工程系应用微生物学研究室，广州 510642 2香港理工大学土木与结构工程学系，香港九龙 3广东省微生物研究所，广州 510070 摘要：为了缓解污水处理厂日益严重的污泥处置难题，实现剩余活性污泥的无害化、减量化、稳定化、资源化利用。采用SBR系统对剩余活性污泥进行10天的驯化，加入4.0g/L的乙酸钠作为发酵培养基碳源和前体物质，累积聚羟基烷酸酯(polyhydroxyalkanoates, PHA)。30℃好氧发酵10 h后，PHA积累达1125mg/L，占污泥浓度（MLSS）的质量分数为35.7%。然后经过离心、烘干、粉碎后模压成型加工成一次性使用的可生物降解材料。使用正交试验进行优化，结果表明：其最佳的物料配比和模压条件为：干污泥：57%；稻草纤维：20%；聚乙烯醇（PVA）：19%；硬脂酸钡：2%；氧化钙：2%；最佳工艺条件为100℃，加热1.5h，此时加工出来的产品具有最优的抗压强度和拉伸强度。以本方法制成的可生物降解花盆其所含细菌总数、粪大肠菌群、蛔虫卵死亡率均达到国标所规定的污泥农用生物安全要求；另外，试样中未检出病毒；其重金属含量也达到国标所规定的污泥农用标准；其可生物降解性能达到了可降解材料的要求。因而本研究制备的一次性使用可降解花盆具有较好的开发和应用价值。 关键词：剩余活性污泥 可降解材料 模压成型 花盆 中图分类号：703 Production of disposable biodegradable materials from excess activated sludge Pang Xu, Hu Wenfeng1*, Chua Hong2, Ouyang Yousheng3, Shi Qingshan3, Zhang Changyong1, Shu Xiuling3 1 Lab of Applied Microbiology, Department of Bioengineering, College of Food Science, South China Agricultural University, Guangzhou 510642 2 Department of Civil and Structural Engineering, The Hong Kong Polytechnic University, Hong Kong. 3 Guangdong Institute of Microbiology, Guangzhou 510070. P.R. China Abstract: This study was carried out to supply a new option for resource utilization of excess activated sludge in urban wastewater treatment plants by making disposable biodegradable material. The excess activated sludge was acclimated for 10d by SBR systems, and then 4.0g / L of sodium acetate was added as the precursor for polyhydoxyalkanoates (PHA) accumulation in the acclimated sludge, with aerobic fermentation for 10 h at 30 (C. The maximum yield of PHA was 1125mg/L, accounting for 35.7% of the mixed liquor suspended solids (MLSS). After centrifugation, drying and mixing, the sludge was molded into disposable biodegradable materials such as disposable flowerpot. To optimize the formula of the biodegradable material, orthogonal experiment has been conducted. The results showed that the optimum ratios of raw materia