玉米秸秆生物炭对Cd2的吸附特性及影响因素.docVIP

玉米秸秆生物炭对Cd2+的吸附特性及影响因素 徐楠楠，2，林大松2，徐应明2, 谢忠雷1*，梁学峰2，郭文娟2 (1.吉林大学环境与资源学院，吉林长春 130012; 2.农业部环境保护科研监测所农业部产地环境质量重点实验室/ 天津市农业环境与农产品安全重点实验室，天津 300191) 摘要：以玉米秸秆生物炭为实验材料，研究了生物炭吸附重金属Cd2+的性能，分析了吸附温度，吸附时间，初始pH值以及生物炭粒径对吸附的影响，并对吸附前后生物炭样品进行傅里叶变换红外光谱分析（FITR）、X-射线衍射( XRD)和X-射线光电子能谱( XPS)表征以分析吸附机理。结果表明：玉米秸秆生物炭对Cd2+的吸附可用Langmuir等温方程较好的拟合，在不同温度下其饱和吸附量分别为18.49 mg·g-1（288.15 K）、23.51 mg·g-1（298.15 K）、23.59 mg·g-1（308.15 K）和24.43 mg·g-1（318.15 K），吸附动力学过程可以由准二级动力学方程很好的拟合，约40 min即达平衡，pH值为5时吸附量最大，生物炭粒径对吸附无明显影响，结构表征表明，生物炭对Cd2+的吸附机理主要为表面羟基（-C-OH）和羰基（-C=O）与Cd2+发生络合化学反应作用。 关键词: 生物炭；镉；吸附；吸附动力学； The Adsorption of Aquatic Cd2+ onto Biochar Obtained from Corn Stalks XU Nan-nan1,2, LIN Da-song2, XU Ying-ming2, XIE Zhong- lei1, Ling Xue-feng2，GUO Wen-juan2 (1.College of Environment and Resources，Jilin University，Changchun 130012，China; 2． Agro-Environmental Protection Institute of Ministry of Agriculture，Key Laboratory of Original Agro-Environmental Quality of Ministry of Agriculture / Tianjin Key Laboratory of Agro-Environment and Agro-Product Safety，Tianjin 300191，China) AIn order to study the adsorption characteristics of biochar obtained from corn stalks on aquatic Cd2+, the batch experiments were carried out to investigate the effects of reaction time, temperature (288.15 -318.15 K), solution pH, and particle size of the adsorbent on the adsorption of aquatic Cd2+ onto biochar in the paper. The surface characteristics of biochar before and after Cd2+ sorption were investigated with X-ray diffraction analysis (XRD), Fourier transform infrared spectroscopy (FTIR) and X-ray Photoelectron Spectroscopy (XPS). The results indicated that the adsorption kinetics can be well described by the pseudo-second order kinetics model, the equilibrium sorption data were better represented by Langmuir model than the Freundlich model, and the maximum adsorption capacity of the biochar for Cd2+ at different temperatures was 18.49 mg·g-1 (288.15 K), 23.51 mg·g-1 (298.15 K), 23.59 mg·g-1 (308.15 K) and 24.43 mg·g-1 (31