三种有机物对LY12CZ铝合金在酸性溶液中的缓蚀.pdf

LY12CZ 41 LY12CZ T hree Organic Corrosion Inhibitors on LY 12CZ Aluminum Alloy in Acid Solution , , , , ( , 1001 1) LIU Jianhua, SH EN G Hua, LI M ing, LI Songmei, YU Mei ( School of M aterials Science and Engineering, Beihang U niversity , Beijing 1001 1, China) : 2( M BIH) ( BTA) 8( 8Q) , LY 12CZ LY 12CZ ( OM) ( FESEM) ( EDS) ; (EIS) , : LY 12CZ ; MBIH BT A 8Q MBIH BTA LY 12CZ S , , , LY 12CZ 8Q , , , : LY12CZ ; ; ; ; : T G 174. 42 : A : 2011) Abstract: T he inhibiting effect of three organic compounds on the corrosion of LY 12CZ aluminum al loy in 0. 5M H2 SO4 solution w as investigated. The organic compounds are 2mercaptobenzoxazole ( MBIH) , benzotriazole ( BT A) and 8hydroxyquinoline( 8Q) . T he inhibiting effect to the corrosion dynamics of LY 12CZ aluminum alloy in 0. 5M H2 SO4 solution w as evaluated by using mass loss meth od and the corrosion morphology w as observed by using optical microscopy ( OM) , scanning electron microscopy coupled w ith energy dispersive spectroscopy ( SEM/ EDS) . Electrochemical impedance spectroscopy ( EIS) and potentiodynamic polarization w ere used to study the inhibiting mechanism. The results show that MBIH, BT A and 8Q all provide anticorrosion protection for LY12CZ alumi num alloy by forming a thin organic layer of insoluble complexes on the surface of the alloy . T heir in hibitive properties are given by the follow ing order: M BIH BT A 8Q. MBIH and BTA provide anti corrosion protection by absorbing selectively on the corrosion active intermetallic zones and suppress ing the cathode proces