al18b4o33wal复合材料表面电沉积ni审审p合金的耐蚀性研究 word格式.docxVIP

al18b4o33wal复合材料表面电沉积ni审审p合金的耐蚀性研究 word格式.docx

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al18b4o33wal复合材料表面电沉积ni审审p合金的耐蚀性研究 word格式

AbstractGenerally, electrodeposition whichisalsocalledelectrophoreticcoating, can achieve allkinds of nanocrystalmaterials whit sizeof 1~100nmunder certainsimpleconditions.Itisamethodthatdeacidizethemetalonthecatelectrodesurface,applyingaexternalvoltagemakesthecurrentflowsthroughthecatelectrode,electrolyte,electrode.Inthispaper,thepreparationofNi-Palloyisbasedonthe electrodepositiononthe surfaceofAl18B4O33w/Alcomposite.By the analyzing tothe pattern of the surface and the histology of thematerial,throughSEM,TEMandXRD,wegettheconsequencethat:thethicknessoftheplatingNi-PfilmisthickeningwhenthecurrentdensityandpH areraising.Eachfilm hasagoodbondingwiththecompositebasis;In theconditionofcurrentdensityis2000A/m2,pHreaches2andthetimeofplatingis3h,thesurfaceoftheplatingNi-Pfilmisthesmoothest,italsohasthebiggestamorphousstate.Noobservationofblowholesandobjectsinnodularform;Enlargingtheplatingtime,thedensityandtheamorphousdegreeofthesurfaceofplatingNi-Pfilmareallbetter,thethicknessisthickening,too;Ni-Pgetsabetterplatingspeedandfirstlydepositsontheareaoftheinterfacebetweenthewhiskersandbase,incomposite.Theanalysisthroughdynamicpolarizationcurvetestingindicatesthat:Enlargingtheplatingtime,thedensity,thecorrosionresistanceofplatingNi-P filmisbetter.EISindicatesthat:Ni-Pplatingfilmitselfobtainsgreatcorrosionresistance.EarlyintheagewhenimmersingintheNaClsolution,thereisaself-repairingprogressofthefilm,thendiametersofthearcsinNyquistgraphisenlargingthrough time, later,arcs falldown.Heat treating experiments indicate: After heat treating in 200℃and400℃,therearecrystalcomposesindifferentgradesonthesurfaceofthefilm, leadingtodifferentcorrosionresistances,obviously.Andtheheattreatingin 400℃make thecorrosion resistance ofthe filmfalling moresharply.Keywords electrodeposition;Ni-Palloy;corrosion;heattreating目录摘要.............................................................................................................................IAbstract.....................................

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