fe xⅲ辐射跃迁性质及gai超精细结构的理论研究 word格式.docxVIP

fe xⅲ辐射跃迁性质及gai超精细结构的理论研究 word格式.docx

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fe xⅲ辐射跃迁性质及gai超精细结构的理论研究 word格式

Thedevelopmentofthelaserspectroscopyandtheadventofpowerfulcoputershave beenlargelytriggedtheinvestigationoftheenergylevels,radiatedtransition,and hyperfinestructureoftheatoms.Meanwhile,thedemandsforpreciseatomicdataare greatlygrowingduetoitspotentialapplicationssuchasdiagnosisofplasmasituationandanalysis ofcelestial spectra. In this thesis, we investigated thefine structure、lifetimes andradiatedtransitionofFeXIII,aswellasthehyperfinestructureofGaandthenuclear momentsofitsisotopesbyusingtheGRASP2Kpackagebasedonmulticonfiguration Hartree-(Dirac-)Fockmethod.Manyattentionshavebeenpaidontheelectroncorrelation effects in atomand ion. The mainworksaredividedintotwoparts:Thefinestructure,lifetimesandtransitionratesofthelevelsbelongto3s23p2、3s3p3and3s23p3dconfigurationsfortheSi-likeironionwereinvestigated.Theelectron correlations,theBreitinteractionandquantumelectrodynamicseffectsweretakeninto accountinthecalculation.Theinfluencesofcorrelationsonphysicalmagnitudeswere analyzedindetail.Itwasfoundthethecore-valence correlation was significant for concernedatomicparameters.Therefore,thecore-valencecorrelationshouldbetaken into account if higher accutatedatawereneeded.Theoreticalcalculationwereperformedonthehyperfinestructureconstantsof 4s24p2P1/2,3/2and4s25s2S1/2statesfor71Ga.Electroncorrelationsweretakenintoaccount systematicallywiththeactivespacemethod.Theinfluencesofcorrelationsonthe hyperfinestructureconstantswereanalyzedindetail.Meanwhile,thecontributionsfrom theBreitinteractionandquantumelectrodynamics(QED)effectstoconcernedatomic parameterswerealsoshown.Basedonaccuratecaculationofthehyperfienstructure,the magnetic dipole moments and electric quadrupole moments for the isotopes wereobtained, good agreement was found betweenour results and experimental values.Keywords:multi-configurationHartree-(Dirac-)Fockmethod,electroncorrelationeffect, relativisticeffect,radiatedtransition,hyperfinestructure,magneticdipolemomentand electric quadrupole momentii摘要………………………………………………………………

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