超音速电弧喷涂耐磨抗蚀铁基涂层的制备和性能研究-材料工程专业论文 word格式.docxVIP

-0.65V提高到-0.58V，而碳化铬涂层中铬和碳化铬以及镍元素的存在，也在一定程度上提高了碳化铬涂层的自腐蚀电位,使得碳化铬涂层的自腐蚀电位由基体的-0.65V提高到-0.61V, 302A涂层与基体拥有相接近的自腐蚀电位。研究了三种涂层在600℃保温120小时的氧化特性。试验结果表明三种涂层均有效的提高了基体的耐高温氧化性能，其中302A涂层和碳化铬涂层的耐高温氧化性能比高铬涂层的耐高温氧化性能更佳。三种涂层表明的氧化膜生成形式均是以选择性氧化优先生成部分氧化膜为主，然后氧化膜逐渐向表面其他区域延伸。涂层的600℃和800℃热震结果表明施加打底层的涂层比未施加打底层的涂层具有更加优良的抗热震性能。而三种涂层中302A涂层的抗热震性能最佳，高铬涂层次之，碳化铬涂层次之，从侧面说明了302A涂层的结合力最高，高铬涂层次之，碳化铬涂层结合力稍差。关键词:超音速电弧喷涂显微组织摩擦磨损性能电化学腐蚀性能耐高温性能AbstractInthispaper,threekindsofcoatingswereprepared bysupersonicarcspraying technology.Accordingtothecompositionofthecoreofwires,thecoatingswere302A coating,highchromiumcoatingandchromiumcarbidecoating.Thesurfaceandcross sectionmorphologyandmicrostructuralcharacteristicsofthreecoatingswereobserved byscanningelectronmicroscopy(SEM),andEnergyDispersiveSpectrometer (EDS)were usedtoanalysethedistributionsofthechemicalelementsandcompositionsofthree coatings.Phasecompositionsofthreecoatingswere analyzedby X-ray diffraction(XRD).Inaddition,microhardness,wearresistance,corrosionresistance,high temperatureoxidationandthermalshockbehaviorsofthecoatingsweretestedwith micro-hardnesstester,weartesterandelectrochemicalworkstationandresistance furnace.Thenthewearandfrictionproperty,electrochemicalcorrosionmechanismand hightemperatureoxidationbehaviorofthe coatingswerestudied and compared.AccordingtotheSEMimagesofthreecoatings,themicrostructureofthreecoatings werewell-distributedandcompact.Mostoftheparticlesdeformationweresufficientto formflakes,somemetallicparticlesdidnotdeformenough.Inthecoatingsfewobvious defectsexisted,butsomeporescouldbeobserved,whiletheporosityofthethreecoatings werelessthan10%.Mostofporesoftenexistedbetweenflakesornearundeformed particles.The microhardnesses were tested on the cross section,the average values werecalculated.Thetestedresultsindicatedthat302Acoatinghadthehighest hardness values,itsaboutfivetimesofthematrixs.Chromiumcarbidecoatingsmicrohardness wassmallerthanthe302Acoating,whichwasfourtimesasthematrixs.Andhigh chromiumcoatinghadthelowest