超重力均相催化臭氧法处理黑索今废水的研究-化学工程专业论文 word格式.docxVIP

进行了对比，发现超重力技术使得 O3/H2O2 和 O3/Fenton 过程的臭氧利用率分别提高了64.5%和 59.5%。针对上述两种均相催化臭氧法处理 12min 内尾气中未被利用的总臭氧量多达 40%左 右的问题，采取以下两种措施进一步提高臭氧利用率：（1）对尾气中的臭氧进行二次 利用；（2）更改储液槽尺寸，以增加臭氧二次利用时的气液接触时间。方案实施后， RPB-O3/H2O2 法和 RPB-O3/Fenton 法的臭氧利用率较原工艺分别提高了 11.2%和 8.4%。 三 种 处 理 方 法 氧 化 效 率 和 臭 氧 利 用 率 的 大 小 关 系 是 ：RPB-O3/Fenton RPB-O3/H2O2 RPB-O3。与其它两种方法比较，RPB-O3/Fenton 法实现 了在最短的时间内达到最好的处理效果，从而大大节省了电耗与臭氧投加量，是一种新 型、高效、节能的 RDX 废水处理方法。关键词：RDX 废水，RPB，臭氧利用率，O3/H2O2，O3/FentonStudy on RDX-containing Wastewater Treatment by Homogeneous Catalytic Ozonation in Rotating Packed BedAbstractRDX-containing wastewater is produced during the production and use of RDX, which will cause serious harm to human health and ecological environment because of its complex composition, high toxicity and low biodegradability. RDX-containing wastewater treatment methods are generally divided into three categories which are physical method, advanced oxidation method and biological method. The energy consumption and cost of the physical and biological methods are low, but when used alone, the physical method has disadvantages of treating not thoroughly, recontamination and low removal rate etc., and the biological method has disadvantages of long degradation time and low degradation efficiency etc.. Chemical method is relatively efficient and completely, but it just greatly improve the biodegradability of wastewater, which is difficult to directly meet the national emission standards. Therefore, the research of a new, efficient and economic method of treating RDX-containing wastewater becomes a current study hotspot.For the lack of an efficient method of treating RDX-containing wastewater, treatment of it by homogeneous catalytic ozonation in rotating packed bed (RPB) was studied in this paper.In the experiment, 700mL RDX-containing wastewater (RDX concentration of 50mg/L and COD=93mg/L) was treated using RPB-O3, RPB-O3/H2O2 and RPB-O3/Fenton respectively. The results show that the latter two treatment methods are feasible.(1