超重力电解含酚废水的基础分析-无机化学专业论文 word格式.docxVIP

为进一步提高废水处理效果，采用电解质强化超重力电解含酚废水，以初始浓度为 3000 mg/L 的含酚废水为对象进行研究。通过不同浓度下，电解质 NaCl 和 Na2SO4 对苯 酚去除效果的对比，选择 NaCl 作为支持电解质。通过研究 NaCl 浓度、超重力因子、电 解时间、电压对苯酚去除率的影响。结果表明，苯酚去除率随着 NaCl 浓度的增加先升 高后降低，随着超重力因子的增加先升高后降低，随着电压的增大而增大，随着电解时 间的增加而增加。随后确定了最适宜的工艺参数为：电解质浓度 0.03mol/L，超重力因 子 34.48，电压 5V，液体循环流量 60L/h，电解时间 30min。在此工艺条件下处理后得 到的苯酚去除率为 42.79%，COD 去除率为 55.81%；与单纯超重力电解相比 B/C 由 0.17 提高到了 0.31，满足了可生化处理的要求。对普通电解、超重力电解、电解质强化超重力电解含酚废水三种废水处理工艺进行 技术经济分析，结果表明：超重力电解法所需电解时间为普通电解的 4/15，所耗电量为 普通电解的 1/3；电解质强化超重力电解法所需电解时间为普通电解的 2/15，所耗电量 为普通电解的 1/9。电解 30min，超重力电解法、电解质强化超重力电解法处理后的苯 酚去除率是普通电解的 3~6 倍，COD 去除率是普通电解的 6~9 倍。综上所述，超重力技术的使用、电解质的加入，使电解法处理含酚废水的效果得到 了提高、电解时间缩短，有望解决电解方法中能耗高、电解时间长的问题，为电解法处 理含酚废水提供更为经济有效的技术手段，为超重力电解法的工业化应用提供理论依据 和实践基础。关键词：含酚废水，超重力，电解，电解质，苯酚去除率，COD 去除率Basic Research of Phenolic Wastewater Electrolysis under HighGravity Field AbstractPhenolic wastewater becomes one of difficult problems in wastewater treatment all overthe world, because of its toxicity, complicated composition, degradation-resistant, high COD value, poor biochemical degradability. The treatment of phenolic wastewater has received attention both at home and abroad extensively. Among all kinds of treatment methods, electrolysis method has the advantages of mild condition, no secondary pollution, green environmental protection. It is known as one of the most promising approach in 21st century. But the bubbles which are produced by hydrogen evolution and oxygen evolution side reaction adhering to the surface of electrode will lead to low utilization rate of electrode, high cell voltage, large energy consumption and poor mass transfer efficiency. The strong centrifugal force which is produced by high gravity technology can make these bubbles rapidly separated from electrode and electrolyte solution, decrease cell voltage, enhance mass transfer efficiency, reduce the reaction time, improve the treatment effect, reduce energy consumption. Therefore, high gravity technology is used to strengthening electrolysis process, to tr