可旋涂的咔唑类磷光主体材料的合成与表征论文终版推荐.docVIP

大连理工大学本科毕业设计（论文） 可旋涂的咔唑类磷光主体材料的合成与表征 Synthesis and Characterization of Solution-Processible Carbazole-Based Host Materials for Phosphorescent Organic Light-emitting Diodes 大连理工大学毕业设计（论文）格式规范 - PAGE 34 - 摘 要 有机电致发光器件（OLEDs）是未来平板显示及白光照明的主要发展方向。在过去二十年里，有机电致发光取得了令人瞩目的成果。它与传统的显示技术相比具有：响应速度快，视角宽，色彩逼真度高，工作温度范围宽，节能并且可实现柔性显示等诸多优点。电致磷光分子结构中引入重金属原子，可以同时利用单重态和三重态能量，理论上可以达到100%的内量子效率，所以电致磷光比荧光材料效率更高。电致磷光器件通常采用主客体结构，主体材料起到举足轻重的作用，它要起到如下作用：分散磷光发光体以防止出现浓度淬灭、将三线态激子束缚在磷光发光体中、具有载流子传输性能等。 目前大部分磷光器件的主体材料都是咔唑类衍生物，这主要是由于咔唑基团具有良好的空穴传输能力及高的三线态能级。因此本文选择硫芴为核心，在其3,6位通过乌尔曼反应引入叔丁基咔唑和二代叔丁基咔唑，设计、合成了两个目标分子G1SF和G2SF，所有的目标化合物都通过了MALDI-TOF-MS和1H NMR等表征手段验证了其化学结构，并利用紫外-可见吸收光谱，荧光光谱，循环伏安法，研究了目标分子的光物理性质和电化学性质。 目标化合物G1SF和G2SF在普通有机溶剂中有较好的溶解性，可以通过溶液旋涂技术来制备磷光器件。G1SF和G2SF发射蓝色荧光，发光峰分别位于406和407 nm，是典型的蓝紫光。通过循环伏安法计算得到化合物G1SF和G2SF的电离势(IP)分别为?5.33 eV和?5.33 eV，这表明G1SF和G2SF有望成为高效的具有空穴传输能力的磷光主体材料。 关键词：电致磷光；硫芴；主体材料；咔唑 Synthesis and Characterization of Solution-Processible Carbazole-Based as Host Materials for Phosphorescent Organic Light-emitting Diodes Abstract Organic light-emitting diodes (OLEDs) have been one of the research focuses in science and industry due to their great application prospects in flat-panel displays and white-light lighting. In the past twenty years, OLEDs has achieved remarkable results. Compared with traditional display technology, the advantages OLEDs are low cost, fast response, high luminescence, wide view angle, low driving voltage, flexible substrates and so on. The phosphorescent organic light-emitting diodes (PHOLEDs) based on transition metal complexes are capable to utilize excitons in both singlet and triplet state and may achieve nearly 100% internal quantum efficiency. For the PHOLEDs, the host materials play key roles such as confinement of the triplet excitons on the emitter, charge transport, suppression of concentration quenching. Until now , the major host materials for PHOLEDs are based on carbazole derivatives, mainly because of their excellent hole transporting abi