5-白炭黑轮胎胎面胶加工 .pptVIP

15. Januar 2003 Steger - Silica Tread I Processing of Silica Tread Compounds白炭黑轮胎胎面胶的加工 Dr.Lothar Steger /范汝良 Rhein Chemie Rheinau GmbH 莱茵化学（青岛）有限公司 Why silica compounds ?为何要用白炭黑胎面？ By applying silica instead of carbon black in tire tread compounds the following results can be achieved : 用白炭黑代替炭黑具有如下优越性能： much lower rolling resistance of the tire 轮胎滚动损失降低很多 much better ice and snow performance 抗冰滑和抗雪滑行能优越很多 much better wet skid behaviour 抗湿滑性能改善很多 at similar tread wear patterns 具有相近的耐磨性 Properties of Silica with respect to Carbon Black 白炭黑与炭黑的性能对比 Requirements Made on Passenger Car Tires in Europe, the USA, and Asia不同地区对承用胎的要求模式 Contents内容 Why is silica increasingly being used in tire application ?为何白炭黑在轮胎上的应用不断增加？ By what means do silica compounds differ from  carbon black compounds in the mill room ? 在混炼车间借助什么工具区别白炭黑与炭黑 Processing Promoter for Silica Tread Compounds 用于白炭黑胎面胶的加工助剂 Advantages of Processing promoters in S-SBR/silica 白炭黑分散助剂用于白炭黑胶料的优点 Reduced compound viscosities降低混炼胶粘度 Improved flow properties in extrusion 改善挤出流动性 Improved flow properties in molding 改善模压流动性 Anti-sticky effect 具有防粘效果 Improved filler dispersion.改善填料分散 Lower energy use in extrusion and calandering降低挤出压延能耗 Considerations When Using Silica/SilaneTechnology白炭黑/硅烷技术应用原理 Hydrophyl Silica吸水性白炭黑 desired for a good silica dispersion 需要良好的白炭黑分散 Highly reinforcing: 高补强性 --Yield stress 产生屈服应力  Very high viscosity很高粘度  Little extrudate shrinkage很小的挤出收缩  Hydrophobe Silica憎水性白炭黑 Hydrophobation is the result of the first coupling reaction between silica and silane憎水是白炭黑与硅烷偶联反应的结果 Not reinforcing: no Yield stress 无补强性，无屈服应力 Low viscosity低粘度 Extreme extrudate shinkage / high extrudate swell高挤出胀大 Mooney viscosity门尼粘度 Dynamics动态性能 G’ little amplitude小振幅弹性模量 G’ big amplitude 大振幅弹性模量 “Payne”-effect Payne 效应 Silica-dispersion 白炭黑分散 Silanisation grade