毕业设计--新型高效催化剂载体的制备推荐.docVIP

新型高效催化剂载体的制备 摘 要：本文通过控制变量法制备活性氧化铝载体，对不同的制备条件（PH值、老化时间、焙烧温度）进行了考察，并对影响反应的参数进行了研究和优化。结果表明，只有在Al(NO3)3溶液的浓度为2 mol?L-1，PH=8，老化时间为24 h，并且保持温度在 800 °C下焙烧6 h时活性氧化铝载体的性能达到最佳。通过采用过量浸渍法制备活性氧化铝负载Co-Ni、Co-Cu、Cu-Ni及Cu-Zn双金属催化剂，并对活性氧化铝载体及催化剂样品进行红外光谱、光学显微镜分析。结果表明，该产品具有较好的晶相和性质并且能够使活性组分均匀的分布。 关键词：活性氧化铝载体；过量浸渍法；焙烧；红外光谱；光学显微镜 The preparation of new and high efficient catalyst carriers Abstract: Through the control of variable methods for preparing activated alumina carrier, different conditions (PH value, aging time, baking temperature) were investigated, and the parameters affecting reaction were studied and optimized. The result shows that the best performance was achieved with Al(NO3)3 solution concentration of 2 mol?L-1 under PH = 8 and the ageing time for 24 h at the temperature of 800 °C and roasting 6 h. Activated Alumina-supported double metals catalyst system Co-Ni, Co-Cu, Cu -Ni and Cu-Zn were obtained by adopting immersion method. The activated alumina carriers and catalyst samples were analyzed By Elemental Analysis, IR and optical microscope. The results showed that the product has relatively good Keywords: Activated alumina carrier; excessive immersion method; roasting method; IR; Optical microscope 目 录 1 绪论…………………………………………………………………………………….1 1.1 课题的意义………………………………………………………………………1 1.2 催化剂载体的概述……………………………………………………………....1 1.2.1 催化剂载体的定义………………………………………………………...1 1.2.2 催化剂载体的种类及作用………………………………………………...2 1.2.3 催化剂载体的国内外研究现状…………………………………………...4 1.2.4 催化剂载体的未来发展方向……………………………………………... 1.3 课题的研究目的和研究内容…………………………………………………....6 2 实验部分…………………………………………………………………………….....8 2.1 实验试剂和仪器………………………………………………………………....8 2.1.1 实验试剂……………………………………………………………..….…8 2.1.2 实验仪器…………………………………………………………………...8 2.2 氧化铝载体的制备…………………………………………….………………...8 2.3 氧化铝载体的表征…………………………………………………………...….9 2.4 负载型催化剂的制备…………………………………………………………...10 2.5 负载型催化剂的活性评价……………………………………………………...11 3 结果与讨论……………………………………………………………………………12 3.1 沉淀pH值的选择………………………………………………………………12 3.2 老化时间及沉淀反应温度的选择………………………………