er3%2b%2cyb3%2b双掺氧化镧钆透明激光陶瓷的制备与性能研究.pdfVIP

摘 要 以碳酸氢铵为沉淀剂，采用共沉淀法制备了Er,Yb:(LaGd) O 激光陶瓷粉体。所得 2 3 最佳工艺条件为：煅烧温度850℃，煅烧时间2h ，pH=7 。真空烧结法制备Er,Yb:(LaGd) O 2 3 透明陶瓷的工艺条件为：终温1750℃保温20h ，1400℃流动空气气氛下保温20h 。得到 陶瓷的平均透过率在62.15%左右。 通过对样品进行XRD 测试，所得粉体的谱图与Gd O 的标准卡片（PDF12-0797 ） 2 3 一致，表明已生成立方相的样品。通过 SEM 分析，平均粒径约为 70nm 。测试了样品 的上转换光谱，结果表明：样品在 548nm 和 662nm 有较强的发射峰，对应 Er3+ 的 4 2 4 4 4 3+ 3+ S3/2/ H11/2→ I15/2 跃迁和 F9/2→ I15/2 跃迁。研究了Er ,Yb 的掺杂摩尔分数对样品发光 强度的影响，并讨论了发光跃迁机制。确定最佳掺杂摩尔分数为：Er3+掺杂摩尔分数 4% ，Yb3+掺杂摩尔分数5% 。 关键词：铒镱掺杂氧化镧钆；共沉淀法；真空烧结法；光谱性能 I 万方数据 ABSTRACT ANano-powder of Er,Yb:(LaGd) O was prepared via coprecipitation with ammonium 2 3 bicarbonate as a precipitant agent. The results show that the optimum conditions for ceramic powders: calcination temperature was 850 ℃,calcination time of 2 h;the value of pH is 7. The Er,Yb:(LaGd) O ceramic was synthesized by cold isostatic-vacuum sintering method. 2 3 The results show that the optimum conditions for ceramic: sintering temperature is 1750 ℃; sintering time is 20h; anneal temperature is 1400℃,anneal temperature is 20h.The results show that the transmittance rate is about 62.15% The properties of the powders have been characterized. The spectra obtained is consistent with