丙烯酸共聚物_有机膨润土复合高吸水性树脂的研究.pdfVIP

安徽农业科学 , Journal of Anhu i A gri. Sci. 2010 , 38 ( 18) : 9792 - 9794 责任编辑 　常俊香 　责任校对 　卢瑶 丙烯酸共聚物 - 有机膨润土复合高吸水性树脂的研究 陈 飞 ,唐宏科 　 (陕西科技大学 ,教育部轻化工助剂化学与技术重点实验室 ,陕西西安 7 1002 1) ( ) ( ) ( ) 摘要　采用丙烯酸 AA 、丙烯酰胺 AM 、丙烯酸甲酯 MA 为单体与有机膨润土复合 ,通过水溶液共聚法制备复合高吸水性树脂 。考 察丙烯酸中和度、单体配比、引发剂用量、交联剂用量、有机膨润土用量、反应温度对产品吸水倍率的影响。得到了最佳聚合反应条件 : ( ) ( ) ( ) 丙烯酸中和度 75% ,单体 n N aAA n∶AM n∶MA = 8 2∶1∶,引发剂用量 0. 25% ,交联剂用量 0. 03% ,反应温度 75 ℃。此条件下制备的 高吸水性树脂对蒸馏水和 0. 9%盐水的吸收倍率分别为 850和 120 g/ g。 关键词　高吸水性树脂;水溶液共聚;膨润土 ( ) 中图分类号　TQ 32　　文献标识码　A　　文章编号　0517 - 6611 2010 18 - 09792 - 03 Research on A cry lic A c id Copolym erO rgan ic Ben ton ite Com b ined H ighhydroph ilia Resin ( CHEN Fe i et a l　 Shaanxi Un iversity of Science and Techno logy, Key L aboratory of Auxiliary Chem istry and Techno logy for L ight and Chem ical Indu stry, M in istry of Education , X i ’an , Shaanxi 7 1002 1) A b stract　 The acrylic acid (AA ) , acrylam ide (AM ) and m ethyl acrylate (MA ) were u sed a smonom ers to compound w ith organ ic benton ite and then the compound h ighhydroph ilia re sin wa s p rep ared by water so lu tion copo lym erization. The influence s of neu tralization degree of AA , monom er m atch , do sage s of p rim er, cro sslink ing agent and organ ic benton ite, and reaction temp erature on the mu ltip lying factor of the p rod uct were inve stigated. The op timum po lym erization condition wa s obtained as fo llow s: the neu tralization degree of AA wa s 75% , the ratio of monom ers n (N aAA ) , n (AM ) and n (MA ) wa s 8 2∶1∶, the p rim er do sage was 0. 25% , the do sage of cro sslink ing agent wa s 0. 03% and the reaction temp erature was 75 ℃. The mu ltip lying factors of h ighhydroph ilia re sin wh ich was p