Poly（DMAEMAcoVP）智能水凝胶的制备及其性能研究毕业论文.doc

本科毕业设计(论文) 题目：Poly（DMAEMA-co-VP） 院 （系）： 材料与化工学院 专 业： 高分子材料与工程 班 级： 学 生： 学 号： 指导教师： 年月Poly（DMAEMA-co-VP） on Preparation and performances of Poly （DMAEMA-co-VP） smart hydrogels Abstract Smart Hydrogel is one of the hot research topic. Most of the smart hydrogels are temperature sensitive or pH-sensitive or both 2-(Dimethylamino)ethyl Methacrylate (DMAEMA), polymers have both temperature sensitive and pH-sensitivity. Moreover, because there is no toxicity and volatility in the chemical components, DMAEMA polymers are also widely used as a kind of biomedical materials and environmentally friendly materials. In this paper, PDMAEMA smart hydrogel and Poly（DMAEMA -co-VP）smart hydrogel are designed and prepared, utilizing DMAEMA and 4-vinylpyridine (VP) as the monomers and N, N-methylene bisacrylamide (BIS) as the crosslinker, The effect of the chemical structure on the swelling kinetics of hydrogels, the temperature sensitivity, pH sensitivity and the adsorption-desorption behavior of heavy metal ions was investigated. The results may provide a clue for the development of experimental and theoretical study of smart hydrogels and expand the scope and applications of smart hydrogels. Key words: N,N-dimethylaminoethyl-methacrylate acrylate; hydrogel; swelling kinetics; temperature sensitivity; pH-sensitive; heavy metal ions 主要符号表 DMAEMA 甲基丙烯酸-N,N-二甲氨基乙酯 VP 4-乙烯基吡啶 AIBN 偶氮二异丁腈 DMSO 二甲基亚砜 BIS N,N-亚甲基双丙烯酰胺 目录 摘 要 I Abstract II 主 要 符 号 表 III 1 绪论 1 1.1 引言 1 1.2 水凝胶 2 1.2.1 水凝胶的定义 2 1.2.2 水凝胶的分类 2 1.2.3 水凝胶的合成方法 3 1.3 智能水凝胶 3 1.3.1 智能水凝胶的定义 4 1.3.2 智能水凝胶的分类 4 1.3.3 智能水凝胶的应用 8 1.4 本论文的研究背景及研究意义 10 1.4.1 本论文的研究背景及意义 10 1.4.2 实验设想 11 2 Poly（DMAEMA-co-VP）智能水凝胶的制备及性能研究 12 2.1 前言 12 2.1.1 甲基丙烯酸-N,N-二甲氨基乙酯的性质 12 2.1.2 4-乙烯基吡啶的性质 12 2.1.3 N,N-亚甲基双丙烯酰胺（交联剂）的性质 12 2.2 实验部分 13 2.2.1 实验原料 13 2.2.2 实验仪器及设备 13 2.2.3 实验原理