有序介孔碳负载过渡金属氧化物催化剂的合成及电催化性能研究-应用化学专业论文.docx

广西师范大学学位论文以聚乙烯吡咯烷酮(PVP)为表面活性剂，采用水热合成法制备MC与过渡单金属氧化物CoO的纳米复合物，研究表面活性剂PVP不同添加量对其氧气还原催化性能的影响。以PVP作为表面活性剂，CoO纳米颗粒在MC上均匀分布。当表面活性剂PVP添加量为1．5g时，所制备的CoO／MC．1．5纳米复合物的比表面积高达290．5m291，使得更多的催化活性位点暴露在表面，从而有助于提高其催化活性。CoO／MC．1．5纳米复合物在ORR反应过程中表现出较正的起始电位以及较高的极限电流密度，其催化过程是一个直接4电子转移途径。除此之外，CoO／MC．1．5纳米复合物在ORR过程中也表现出较高的稳定性。关键词：燃料电池；水热合成；有序介孔碳；过渡金属氧化物；氧气还原；氧气析出万方数据广西师范大学学位论文SynthesisandelectrocatalyticpropertiesoftransitionmetaloxidecatalystsgrownontoorderedmesoporouscarbonPostgraduate：LiPengxiSupervisor：PengGuihuaWangJiachengMajor：AppliedChemistryOrientation：EnergymaterialsAbstractTransitionmetaloxidesaleavitalcomponentofthefuelcellcathodecatalysts，whichhavethe advangtagesoflowcost，simplepreparation，extensivesources．Moreover’theypossessthepotentialcatalyticactivitiesforoxygenreductionandoxygenevolutionreactions．Inthispaper,theorderedmesoporouscarbonusedasthesuppoawaspreparedbyaconventionalnanocastingstrategyusingamesoporoussilicarodasahardtemplate．Transitionmetaloxidesnanoparticles(monometal，bimetal，trimetal)weresuccessfullyinsitugrownontoorderedmesoporouscarbonbyafacile，scalablehydrothermalmethod．Thecatalyticactivitiesforoxygenreductionandoxygenevolution‘reactionswereinvestigatedviaconventionalthreeelectrodesysteminbasicsolutions．CoFe204nanoparticlesgrownontoorderedmesoporouscarbonwiththeCTABassurfactantweresynthezised byhydrothermalmethod，followedbyannealing atdifferenttemperatures．Theas—acquiredCFO／MCnanohybridpyrolyzedat400。C(CFO／RC-400)hasahighspecificsurfacearea(150．3m2分1)andtwosetsofuniformmesoporesystems(3．38and19．1nm)，allofwhicharefavorablefortheimprovementoftheelectrocatalyticactivity．ThehybridizationofCFOnanoparticlesandtheMCmatrixresultsinincreasedORRandOERelectrocatalyticactivityoftheCFO／MCnanohybrids．CFO／RC一400showsbettercatalyticactivityfortheORRwithadirectfour-electronreactionpathwaythanthosepreparedatothertemperaturesintermsoftheonsetpotentialandlimitingcurrentdensity．Furthermore，theCFO／MC-400nanohybridexhibitsoutstandingdurabilityforboththeORRandOER，andcanoutperformcom