添加镁锆砂及环保沥青对低碳镁碳砖性能影响的研究-材料学专业论文.docx

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添加镁锆砂及环保沥青对低碳镁碳砖性能影响的研究-材料学专业论文.docx

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添加镁锆砂及环保沥青对低碳镁碳砖性能影响的研究-材料学专业论文

第1I页武汉科技大学硕士学位论文Abstractwinlthedevelopingofexternalrefiningtechnology,，lowcarbonmagnesia-carbonrefraetoriesbecamearesearchhotspotofthemagnesia-carbonrefractories．TIlisworkoverviewedthedevelopmentandthedrawbacksoflOWcarbonmagnesia-carbonmaterial，itrequireschampionstrength，antioxidation,eorrodibilityresistanceandthermalshockresistanceandSOon．Accordingtotherequirementsabove，thispaperstudiedtheeffectofMgOparticlesize，MgOgranularity,magnesia-zirconiapowdersizeandcontent,pitchcontentonstructuroandconventionalpropertiesoflOWcarbonmagnesia-carbonrefractoties．Aftersinteredfordifferentexperimentalintentions，thebulkdensity,apparentporosity,coldcrushingstrengthandhi2911temperaturebendingstrengthofthespecimensweredetermined,respectively．Besidespropertiesabove，antioxidationresistance，thermalexpansion，thermalshockresistanceandcorrodibilityresistancealsodetermined,thephasecompositionandmicrostructurewereobservedbyX-raydiffractioninstrument,scanningelectronicmicroscope,respectively．Then，conclusionsareobtainedasfollows：1)MgOparticlesizeplaysanimportantroleinimprovingthepropertiesoflowcarbonMgO·Crefractories．ReducingMgOgranulesize，theapparentporosity,poresizeofsampleandthermalstressbecamesmaller,the bulkdensity,compressivestrengthimproved，andthethermalexpansionofspecimensreduced．Besides，theporesizediminished，thespeedof02diffusionslowed，andthatcanimprovetheoxidationresistance．2)Reduce magnesiapowercontentandincreasemagnesiaparticlecontent，itCancausethelowcarbonmagnesia-carbonrefractotiestohavethegraphiterelativecentralismphenomenon,andthiscanreleasethermalstress，andispropitioustoenhancethematerials’oxidationresistanceandcorrosionresistance．3)Theinfluenceofparticlesizeandquantityofmagnesia-zirconiapowderonpropertiesoflowcarbonmagnesia-carbonrefractorieshasbeeninvestigated．Theresultsindicatedthat．becauseofthenaturecharactersofmagnesia-zirconiapowder,suchas，bigbulk density,goodcorrosionresistanceandphasetransformationtougheningofzirconia,bethparticleandpowderCanimprovethephysicalpropertie