桐油改性光交联材料的合成与性能研究-应用化学专业论文.docx

乙二醇酯）。在控制比列前提下，将合成所得氨酯二醇与酸酐改性桐油 TM 反应，获得含有羧基的氨酯改性桐油，继而以甲基丙烯酸缩水甘油酯封端，合成了 NIPU改性马来化桐油的光交联树脂。通过如前所述的各类表征、测试，研究发现，氨 酯二醇单体分别与 TM1、TM2 反应得到不同性能的树脂，TM2 系列树脂的分子量和粘度均高于 TM1 系列树脂，同时由于双键含量的不同，TM2 系列树脂的光 固化速率更快，最终双键转化率略低。树脂固化膜的热性能也有所不同，ICD 改性的桐油氨酯丙烯酸酯固化膜的玻璃化转变温度略高于 PCD 改性的桐油氨酯丙烯酸酯，耐热性能也更优异；固化膜的其它性能诸如硬度、附着力、耐酸性、耐 水煮性都很优异，但其耐碱性差，不同树脂之间的差别不大。关键词：光交联，桐油，马来酸酐，羟基丙烯酸酯单体，非异氰酸酯聚氨酯AbstractIn 21th century, more and more attention has been paid to the environment protection and resource saving. Lot of new technologies and products for environment protection and energy saving emerged in each society filed. The application of irradiation curing technique and development of bio-based materials turned to be hot research projects. Irradation curing has been widely employed in products manufacture and honored as green technique due to the outstanding performance in environmentprotection, energy saving, safety ， high efficiency and perfect film properties. On theother hand, for the shortage of petroleum, great effort has been made to develop polymer materials with high quality based on renewable resources and partially replace the pertrolum materials.In this work, renewable and reactive Tung oil was combined with green and efficient UV-curing technique. Tung oil was modified with different functional monomers to obtain a series of photo-curing materials. The relationship between the structure and performance of modified Tung oil was investigated through molecular design, structure modification and property examination. The modification technique and the obtained UV-curable Tung oil resin were also evaluated from the point of view of coating application.Tung oil was used as conjugated diene for modification via a Diels-Alder reaction with maleic anhydride. The maleic Tung oil, TM1 and TM2 were obtained by changing the ratio of tung oil to maleic anhydride. Then TM was modified with two different hydroxyalkyl acrylate monomers: 2-hydroxyethyl acrylate (HEA), Pentaerythritol triacrylate (PETA),