BASF助剂-聚烯烃应用--抗氧剂_紫外线吸收剂.pdf

Additives for polyolefi ns Plastic Additives UV protection of plastics Global solar irradiance 1 kLy = 41.84 MJ / m², Data provided by the Ozone Processing Team at the NASA Goddard Space Flight Center. This map depicts the global variation of average irradiation energy reaching the earth’s surface. UV irradiation energy is responsible for light induced deterioration of plastics and other materials. Therefore, light stabilizer formulations must consider the global location where the fi nal article is used and its expected service life. Absorption characteristics of UV absorbers Individual polymers are affected by different wavelengths. Choosing the most effective light stabilizer for a given substrate depends upon matching the right UV absorber with the susceptible wavelength range of the polymer. UV sensitivity and UV absorbers for PE UV sensitivity and UV absorbers for PP Fraction of electromagnetic radiation reaching Fraction of electromagnetic radiation reaching the earth’s surface the earth’s surface PE PE PP PP 260 280 300 320 340 360 380 400 420 260 280 300 320 340 360 380 400 420 Wavelength (nm) Wavelength (nm) ® ® ® ® Tinuvin 326 Tinuvin PA 328 Tinuvin 231 Chimassorb 81 PP PP extrusion PE PE extrusion