1-s2.0-S0016236115002598-main文档.pdfVIP

Fuel 153 (2015) 102–109 Contents lists available at ScienceDirect Fuel journal homepage: www.else /locate/fuel Understanding the primary and secondary slow pyrolysis mechanisms of holocellulose, lignin and wood with laser-induced fluorescence Alba Dieguez-Alonso a,⇑, Andrés Anca-Couce b, Nico Zobel c, Frank Behrendt a a Technische Universität Berlin, Institute of Energy Engineering, Chair for Energy Process Engineering and Conversion Technologies for Renewable Energies, Fasanenstr. 89, 10623 Berlin, Germany b Institute for Process and Particle Engineering, Graz University of Technology, Graz, Austria c Fraunhofer Institute for Factory Operation and Automation IFF, Magdeburg, Germany h i g h l i g h t s Primary and secondary pyrolysis reactions investigated in a fixed-bed reactor. LIF applied to on-line characterization of aromatic species in pyrolysis volatiles. Pyrolysis of wood and cellulose and lignin as its two main macromolecules. Heterogeneous secondary reactions detected in slow pyrolysis at low temperatures. Lignin identified as the main PAHs formation source in wood pyrolysis. a r t i c l e i n f o a b s t r a c t Article history: To understand the complex reaction mechanisms involved in biomass pyrolysis, volatile products are Received 5 November 2014 characterized on-line by laser-induced fluorescence (LIF), together with on-line measurements of perma- Received in revised form 4 February 2015 nent gases by GC-TCD (Gas Chromatograph-Thermal Conductivity Detector) and temperature evolutions Accepted 22 February 2015