(杨翔真)轻化工程 造纸Detoxification of Kraft pulp ECF bleaching effluents by.pdf

ARTICLE IN PRESS WA T E R R E S E A R C H 4 1 ( 2 0 0 7 ) 9 1 5 – 9 2 3 Available at journal homepage: /locate/watres Detoxification of Kraft pulp ECF bleaching effluents by catalytic hydrotreatment ´ L. Calvo , M.A. Gilarranz, J.A. Casas, A.F. Mohedano, J.J. Rodrıguez ´ ´ Seccion de Ingenierı´a Quı´mica, Facultad de Ciencias, Universidad Autonoma de Madrid, Cantoblanco, 28049 Madrid, Spain a r t i c l e i n f o a b s t r a c t Article history: Two different effluents from the D1 and E1 stages of the ECF bleaching of Eucalyptus globulus Received 24 July 2006 kraft pulp were treated by catalytic hydrogenation in a trickle bed reactor using commercial Received in revised form and homemade Pd/AC catalysts. The reactor was fed with the bleaching effluent and a 13 November 2006 H2/N2 gas stream. The variables studied were space-time (1.4–5 gcat min/mL), gas to liquid Accepted 13 November 2006 flow ratio (286–1000 vol.), gas feed concentration (H :N , 1:1–1:7.3 vol.), temperature 2 2 (25–100 1C) and pressure (1–11 bar). Hydrotreatment performance was evaluated in terms Keywords: of ecotoxicity, adsorbable organic halogen (AO