应用化学毕业论文汇.docVIP

应用化学毕业论文 非线性光学聚氨酯复合材料的研究 专业 应 用 化 学 非线性光学聚氨酯复合材料的研究 摘要： 本文以制备具有高非线性活性和热稳定性的非线性光学聚合物材料为目的，设计合成了新型具有高二阶极化率的噻唑生色分子，制备了两种新型非线性光学聚氨酯复合材料，并对它们的结构和性能进行了研究。 1 设计、合成了含羟乙基活性基团的噻唑类非线性生色分子，用IR1H MNR、UV-Vis和DSC-TG等对其结构和性能进行了表征，用超瑞利散射技术测定了其二阶极化率。结果表明：两种噻唑类生色分子具有较高的β值，在波长1064 nm处，β分别为560×10-28和576×10-28 esu，其最大吸收波长都未超过600 nm，截止波长均小于710 nm，生色分子的热分解温度分别为 224和216 ℃，具有较好的热稳定性，可用于制备性能优异的非线性材料。非线性噻唑生色分子超瑞利散射Research of Nonlinear Optical PU Composite Material Abstract: In this paper, in order to prepare nonlinear optical polymer materials with high nonlinear optical activity and thermal stability, nonlinear optical thiazole chromophores with high β values were designed and synthesized, two kind of nonlinear optical polyurethane composite materials were prepared, and the structures and properties of them were researched. 1 Two nonlinear optical thiazole chromophores with active hydroxyethyl group were designed and synthesized. The structures and properties of the organic molecules were characterized by IR, elemental analysis, 1H MNR, UV-Vis and DSC-TG . The second order nonlinear optical properties of both were determined by hyper Rayleigh scattering method. The results show that the compounds have high β values of 5.60×10-28 and 5.76×10-28 esu at 1064 nm wavelength, respectively. The maximum absorption wavelengths of the compounds were less then 600 nm, and their critical wavelengths below 710 nm. These compounds were thermally stable with the decompounded temperature of 224 and 216 ℃, respectively, and consequently they could be considered to be better choices for the preparation of NLO materials. 2 Novel PU-DR19-SiO2 nanocomposite material was prepared firstly by hydrolysis and condensation of alkoxysilane dye, polyurethane (PU) containing alkoxysilane and tetraethoxysiliane (TEOS) together through Sol-Gel process. The structure and properties were characterized by IR, SEM, TEM, Uv-vis and DSC-TGA measurements. The result showed that the organic phase connect with inorganic phas