改性钙基粘土对湖泊水体及沉积物磷的固定效果研究.docVIP

热处理富钙凹凸棒黏土吸附磷的影响因素研究 孔 明1尹洪斌2, 3, 张毅敏1, 彭福全1* 1.环境保护部南京环境科学研究所, 江苏 南京 2100422.中国科学院南京地理与湖泊研究所, 湖泊与环境国家重点实验室, 江苏 南京 2100083.河海大学环境学院，南京210098 摘要：以800 ℃热处理富钙凹凸棒黏土（记为NCAP800），通过批处理试验和动态试验研究了不同因素（pH、竞争离子、对NCAP800吸附磷的能力的影响。结果表明磷的吸附，对NCAP800的磷吸附pH对NCAP800磷吸附能力的影响主要通过改变黏土矿物中矿物表面。HCO3-对磷的抑制作用为显著，ρ(HCO3-)在5～mg/L时，其次是SO42-，NO3-Cl-对磷的吸附抑制作用。HCO3- 和SO42-钙的结合位点，从而降低了NCAP800对磷的吸附能力。低浓度～的对磷的吸附抑制作用较，高浓度5～0mmol/L）的对磷的抑制作用较为显著，对磷是通过竞争NCAP800表面的磷吸附位点。研究显示NCAP800在碱性条件下对磷具有较好的吸附作用，HCO3-和SO42-及高浓度柠檬酸均会抑制NCAP800对磷的吸附。 关键词：富钙凹凸棒；热处理 ；磷；吸附效率；影响因素 中图分类号：X703 文章编号： 文献标志码：A DOI： Study on influencing factors of phosphorus adsorption capacity of thermally modified calcium-rich attapulgite KONG Ming1, YIN Hongbin2, JI Zhongxin1,3 , ZHANG Yimin1, PENG Fuquan* 1.Nanjing Institute of Environmental Science, Ministry of Environmental Protection, Nanjing 210042, China 2.State Key Laboratory of Lake Science and Environment, Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing 210008, China 3.School of Environment，HoHai University，Nanjing 210098, China Abstract: In this study, influencing factors (pH, competing anions and citric acid) of phosphorus adsorption capacity of 800℃-heated calcium-rich attapulgite were studied. The results showed that pH had no influence on phosphorus adsorption capacity in acidic conditions, while in alkaline conditions, pH had a certain effect on the phosphorus adsorption when it’s in the range of 8~10. The effect of pH on phosphorus adsorption capacity was mainly via changing the amount of exchangeable metals (Mg and Ca) and the Zeta potential. It was noted that HCO3- inhibited phosphorus adsorption of NCAP800 mostly when the concentration of HCO3- is 5～mg/L, followed by SO42-, NO3- and Cl- had no effect on phosphorus adsorption, and the?inhibiting?effect was mainly?through competing?adsorption?sites, which reduced phosphorus adsorption capacity of NCAP800. It was found that low citric acid concentration（0～er effect on phospho