aumexoyme=ni mn la co ce催化剂的制备 表征及其丙烷燃烧催化性能研究word格式论文.docxVIP

中 文 摘 要液化石油气（LPG）是一种应用越来越广泛的汽油代用品，其主要 成分为丙烷和丁烷。当其通过尾气排放到大气中时，就成为空气中 VOCs 的重要来源。其解决方法主要包括催化燃烧法、吸附法和紫外光降解法， 其中催化燃烧法是一种高效且环境友好的治理方法。但是传统的燃烧方 式能量利用率低，易形成 CO、NOx 等污染物。因此具有低温催化性能催 化剂的制备成为研究者追求的目标。（1）制备了 p-型半导体 NiO、MnOx 和 La2O3，n-型半导体 Co3O4 和 CeO2，并对其进行了 XRD、N2-吸附脱附、H2-TPR、UV-Vis、XPS、TEM 和原位电导等表征，并考察了对丙烷完全燃烧反应的催化性能。（2）采用沉积-沉淀法制备了不同金负载量的 xAu/NiO、xAu/MnOx、 xAu/La2O3、xAu/Co3O4、和 xAu/CeO2 催化剂。实验结果表明，金的引入 有利于降低丙烷完全燃烧温度，金的负载量对催化活性有较大影响，其 中活性最好的为 2Au/NiO、3Au/MnOx、3Au/La2O3、1Au/Co3O4 和 4Au/CeO2 催化剂，以上催化剂上丙烷完全燃烧温度分别为 355℃、250℃、435℃、 225℃和 420℃。金的颗粒大小及分散度是影响催化活性的重要原因。（3）p-型半导体 NiO 和 MnOx 上，负载活性组分金后，催化剂的半 导体性质由 p-型转变为 n-型，自由电子浓度增加，反应活性提高。而 n-型半导体 Co3O4 上，随着活性组分金的引入，催化剂由 n-型转变为了 p-型半导体，p-型半导体空穴能位比 n-型半导体导带能位更低，接受电子 速率更快，反应活性提高。关键词金催化剂，沉积沉淀法，半导体氧化物，丙烷完全燃烧ABSTRACTLiquefied petroleum gas is one kind of gasoline substitute which has wide application. Its main components are propane and butane.When propane exhaust to air, it will become an important source of VOCs.The solution methods of VOCs includes: catalytic combustion, adsorption and UV degradation.The catalytic combustion is an efficient and environmental friendly method. But the energy utilization rate of traditional combustion is very low and easy to form pollutants like CO and NOx. Considerable interest has been focused on the catalysts with high performance under lower temperature.(1)p-type semiconductor NiO、MnOx and La2O3，n-type semiconductorCo3O4 and CeO2 were prepared and then the catalysts were characterized by XRD, N2-sorption, H2-TPR, UV-Vis, XPS, TEM and In-situ electrical conductivity measurement. Catalytic performance for the propane combustion was investigated.Different gold loading xAu/NiO, xAu/MnOx, xAu/La2O3，xAu/Co3O4,and xAu/CeO2 catalysts were prepared by deposition-precipitation method. The experimental results show that Au can reduce the total combustion temperature of propane. The gold loading affects the catalytic performance,which the 2Au/NiO, 3Au/MnOx, 3Au/La2O3,1Au/Co3O4 and 4Au/CeO2 catalysts show better