fe3o4复合纳米粒子和金纳米棒的制备与分析应用分析word格式论文.docx

reagents.Third，in the basis of Seed growth method，A new method which based on situ growth of for preparation gold nanorods was Proposed.The method make the seedpreparation， growth medium preparation and growth of gold nanorods get togetherwith organic， simplifying the experimental steps. analyzed and researched the amount of Cetyltrimethylammonium bromide 、auric chloride acid、Ascorbic acid、 Silver nitrate Combine with UV-visible spectrophotometer. At the same time ， Investigate The effects of reaction time， temperature and other conditions onpreparation of gold nanorods. Experiment by adjusting the quantity of sodium borohydride to achieve controllable aspect ratio(vertical/ horizontal) of Gold Nanorods Under the optimal conditions. The gold nanorods were preparation by this method have a good uniformity and reproducibility.Fourth， established a new method for Hg2+ determination based on the goldnanorods， which use Hg0 and Au0 have a special physical and chemical Reaction ， use the strong reduce agent to reduction Hg0 to Hg2+ which deposited at both ends of gold nanorods，to make it produce ablation effect. the longitudinal maximum absorptionwavelength of gold nanorods have the effect of blue shift with Increase concentration of Hg2+ show by UV - visible absorption spectra. Hg2+ at 0.5 ~ 10 μmol/L concentrationrange with good linearity， the detection limit of SDS Determination was 0.25 μmol/L.The method was simple and with high selectivity.Keywords: Polyacrylic acid-coated magnetic nanoparticles，sodium dodecyl sulfate， methylene blue，gold nanorods，Mercury ion1 绪论1.1 纳米材料概述纳米科学是 20 世纪 80 年代发展起来的新领域，它的出现使得人们改造自 然的能力从宏观直接延伸到了分子、原子等微观水平，标志着人类科学进入了 一个新时代，以纳米技术为中心的新科技革命必然成为本世纪的发展的主导， 纳米技术涉及到物理、化学、生物、材料、电子等多个领域及其交叉学科，同 时科学家在了解这些无与伦比的材料及其有用的特性方面已经取得了很大的进 展，已经用纳米材料做出了各种产品——从陶瓷到电子产品，它们肯定还会在无 数其他领域找到更为广泛的应用。事实上，纳米技术的应用是多方面的，将引导 众多传统产业的改造升级，激发新的工业革命。纳米级结构材料简称为纳米材料(nano material)，是指其结构单元的尺寸介 于 1~100 纳米范围之间。是处在原子簇和宏观物体交界的过渡区域，从通常的 关于微观和宏观的观点看，这样的系统既非典型的微观系统亦非典型