基于ho-pdlla-oh的可生物降解聚氨酯及其蒙脱土复合材料的研究-study on biodegradable polyurethane and its montmorillonite composites based on ho - pdl la - oh.docxVIP

ABSTRACTA new kind of block copolymers were made from the molecular designing, using D,L-lactide, 1,6-hexamethylene diisocyanate, 1,4-butanediol and 1,4-butanediamine. These block copolymers with strong hydrophilicity, thermosensitive, controllable acidity of degradation, is a kind of biodegradable poly(D,L-lactic acid)-polyurethane. Furthermore, preparing poly(D,L-lactic acid)-polyurethane /montmorillonite nano- composites using solvent method. These products were characterized by fourier transform infrared spectrometry (FTIR), nuclear magnetic resonance spectrometer (NMR), differential scanning calorimeter (DSC), X-ray diffractometer (XRD) and the classical chemical analysis to explore the structures and the properties. The main works and conclusions are included as follows:HO-PDLLA-OH was synthesized by melt ring-opening polymerization of D,L-lactide and butanediol with Sn(Oct)2 as a catalyst. The results of the reactive time and the reactive ratio of D,L-lactide and butanediol on the molecular weight, structures and properties were discussed.① FTIR, NMR, and chemical analysis showed that HO-PDLLA-OH wassuccessfully synthesized as a copolymer from D,L-lacide and butanediol.② As the reactive ratio of D,l-lactide and butanediol is 25:1, the Mw of product is 3600; and the molecular distribution of this copolymer is narrow when the reactive time is 24h.③ The glass transition temperature of HO-PDLLA-OH by DSC was 36.33℃,whose molecular weight is 3600.A kind of linear copolymer from HO-PDLLA-OH, HDI and BDA was made in solution with Sn(Oct)2 as a catalyst. The reactive activity of HO-PDLLA-OH and HDI from the water content of reaction system, the ratio of catalyst and the reactive temperature were discussed, and in exploring the structures and the properties of these products.① The water content of reaction system was far less than that possibly to consumeHDI after the non-aqueous treatment.② FTIR, NMR, and chemical analysis claimed that the copolymer is a type