基于四苯乙烯与蒽衍生物有机电致发光器件制备与性能分析-preparation and performance analysis of organic electroluminescent device based on tetrastyrene and anthracene derivative.docxVIP
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基于四苯乙烯与蒽衍生物有机电致发光器件制备与性能分析-preparation and performance analysis of organic electroluminescent device based on tetrastyrene and anthracene derivative
苏州科技学院硕士学位论文摘要摘要有机电致发光器件(OLED)具有发光强、视觉宽、响应速度快、驱动电压低等优点,被认为是最具发展前景的新一代显示技术。近年来,许多科研机构都在为平板显示产业的发展做着积努力,同时也取得了令人瞩目的成就。本论文的主要研究内容如下:(1)对四苯基材料TMTPE和TBTPE的聚集态效应进行了研究。发现它们都是聚集态增强材料,体现了聚集诱导发光增强(AIEE)效应。利用TMTPE作为发光层,采用真空镀膜法制备了OLED器件,经测试后得到的结论如下:四苯乙烯材料聚集分为两个阶段:第一次聚集在荧光量子产率方面显示出突变,急剧增强是荧光小分子规则的直线排布所致;第二次聚集表现在荧光量子产率数值平缓地增强,是溶液中分子发生了无序的堆积所致。利用材料TMTPE作为发光层制备了OLED器件,表现出的结果是一个器件有两个强的发光带:第一个发光带处于蓝光光谱范围,来自第一步聚集;第二个则处于黄光发光带,来自第二步聚集过程,该器件的发光覆盖了整个发光光谱,属于白光的范畴。当外界施加电压为8V到13V时,其CIE色坐标为(0.333,0.358),这就证实了TPE类有机材料可用于作为单层发光材料来制备白光电致发光器件。(2)对蒽类材料DPA-Cl和DPA-CN进行了光电性能研究。在光学性能方面,DPA-Cl具有聚集态猝灭效应,其荧光量子效率较高。而在电学性能方面,发现利用DPA-
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