四平市条子河典型区段沉积物中PAHs的分布特征研究.docVIP

四平市条子河典型区段沉积物中PAHs的分布特征研究 摘要 多环芳烃是持久性有机污染物的一种，具有持久性和致癌性，其含量低，但是毒性大，脂溶性较好，可通过食物链富集在处于食物链顶端的生物体内，对人类的身体健康造成极大的威胁。 本文利用低温保存、超声波萃取、硅胶层析柱净化、气相色谱-质谱联用相结合的方法，对分别于2012年10月、12月和2013年4月采集的条子河典型区段的8个底泥样品中的多环芳烃进行了测定分析，结果表明：位于上游且距离四平市市区较近的汇河口地区的河段底泥中多环芳烃的含量最高；由于冬季燃煤量的增加，2013年4月采集的样品中所含多环芳烃总量明显大于2012年10月和12月；此外，在采集到的8个样品中只检测到了中低环的PAHs，而几乎没有高环的PAHs出现，而且低环的PAHs比中环的含量高。最后通过分析多环芳烃的来源，为多环芳烃污染的防治提出合理的建议。 关键词：条子河，底泥，多环芳烃，含量 The distribution characteristics of PAHs inthe sediments of TiaoZi river’s typical sections around SiPing Author：Qi Zhang Abstract Polycyclic aromatic hydrocarbons, which is a kind of persistent organic pollutants (pops), with persistence and carcinogenicity, its content is low, but is toxic, fat soluble, can be through the enrichment of the food chain at the top of the food chain organisms, poses a great threat to human health. Based on low temperature preservation, ultrasonic extraction, silica gel column chromatography purification, gas chromatography - mass spectrometry method of combining the, to, respectively, in October 2012, December and April 2013 acquisition of sliver river sections of eight typical polycyclic aromatic hydrocarbons in the sediment samples was determined by analysis, the results show that located in the upstream and SiPingShi from close to the righteousness of the estuary of river sediment content of polycyclic aromatic hydrocarbons in the highest; Due to the increased amount of coal in winter, in April 2013, collection of samples is bigger than the total polycyclic aromatic hydrocarbons contained in October 2012 and December; In addition, the collected eight samples detected only in the middle and lower ring PAHs, and almost no GaoHuan PAHs, high and low ring PAHs than central content. Finally through the analysis of the sources of polycyclic aromatic hydrocarbons, multiple pah pollution prevention put forward reasonable Suggestions. Keywords: striped river，sediment，polycyclic aromatic hydrocarbons， content 前言 1 第1章　绪论 2 1.1研究背景及意义