水泥基复合材料韧性提升技术与微观机理分析.docVIP

水泥基复合材料韧性提升技术与微观机理分析 //.paper.edu.cn - 1 - 水泥基复合材料韧性提升技术与微观机理 分析# 郭丽萍1,2，张文潇1，金林洪1* 基金项目：国家自然科学基金(编号;高等学校博士学科点专项科研基金资助课题(编号 20090092120037);高性能土木工程材料国家重点实验室开放基金资助(编号 2010CEM005) 作者简介：郭丽萍（1979-），女，副教授，博导，主要研究方向：复杂因素作用下水泥基复合材料多尺度 损伤研究 （1. 东南大学材料科学与工程学院，南京 211189； 5 2. 江苏省土木工程材料重点实验室，南京 211189） 摘要：本文采用单掺水溶性聚合物及其与有机/无机纤维复合技术对水泥基材料进行增韧。 通过压折比、弯曲荷载-位移曲线积分面积表征材料韧性的方法，对上述增韧技术的增韧效 果进行了评价。结果表明，单掺聚合物对于水泥基材料的增韧效果欠佳，而聚合物与聚乙烯10 醇纤维复合增韧效果最显著，比基准砂浆提高了 5 倍以上。此外，通过采用环境扫描电镜对 其微观机理分析可知：不仅聚合物能在水泥基体均匀成膜，形成网络状结构，而且聚乙烯醇 纤维与聚合物化学相容性好，减少了基体-纤维界面区的微裂纹，从而显著改善了基体、基 体-纤维界面区的材料匀质性和粘结强度，提高了水泥基材料的韧性。 关键词：水泥基复合材料；韧性；聚合物；纤维；细观损伤；栅格模型 15 中图分类号：TU528 Research on Toughening Technology and Microscale Mechanism of Cement-Based Composites GUO Liping 1,2 , ZHANG Wenxiao 1 , JIN Linhong 1 20 (1. School of Materials Science and Engineering, Southeast University, Nanjing 211189; 2. Jiangsu Key Laboratory of Construction Materials, Nanjing 211189) Abstract: Three types of water-soluble polymers and three categories of inorganic/organic fibers were optimized with single-doped or doped complex for improving toughness of cement-based materials. The toughening effect of cement-based materials was evaluated by the 25 compressive-bending strength ratio and the integral area of bending load and displacement curve. The results show that single-doped polymers have poor toughening effects on cement mortar, however, combining polymers with polyvinyl alcohol fiber have significant effects on toughness of cement motor, which are more than 5 times higher than the reference mortar. Furhtermore, the microscale mechanisms of toughened cement-based materials were also investigated by 30 environmental scanning electric microscopy. Because the film-forming polymer can uniform the cement matrix by a network structure as well as the polyvinyl alcohol fiber has better chemical compatibility with polymers, not only the homogeneity and