沉淀法制备镍催化剂及其提高次氯酸钠氧化性能的研究.pdf

无机盐工业 第 42卷第 9期 14 INORGAN IC CHEM ICAL INDU TRY 2010年 9月 1 2 2 2 2 , , , , ( 1. , 210048; 2. ) : /, , BET - , : , ; 450 ; 14% (); 14% 450 ( CODcr) 6 000 m g/L, CODcr 5 554 m g/L, CODcr 600 m g/L, : ; ; ; : TQ138. 13 : A : 1006- 4990( 2010) 09- 0014- 04 - Im proving oxidation perform ance of NaC lO w ith N ibased catalyst prepared by imm erse prec ip itation m ethod 1 2 2 2 2 hu Changhao, hen Chen , M eiHua, hi X iaopeng , YaoHuqing ( 1. Ref inery Plant of Sinop ec YangziPetrochemical Comp any Ltd.,N anjing 210048, China; 2. School of Chemistry and Chem icalEng ineering, Nanjing niversity of Technology) A bstrac t: upported N-ibased catalyst w as prepared by mi m ersion precip itation m ethod w ith A l O /MgO as carrier. 2 3 Prepared catalyst was characterized by BET, environmental scann ing electronic m icroscope, and therm ogravmi etry and the catalytic perform ance thereof in decom pos ing sod ium hypochlorite ( NaC lO) to produce active ch lorinew as also studied. Re - su lts show ed that pore size distribution of N ibased catalyst m ainly concentrated in the m esopores, w hich w as in favor of in creasing catalytic activity; su itable calcination tem perature forN-ibased catalyst w as450 ; proper load ing am