基于1,2,4,5-苯四甲酸构筑金属有机配合物-building metal-organic complexes based on 1,2,4,5 - benzenetetracarboxylic acid.docx

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基于1,2,4,5-苯四甲酸构筑金属有机配合物-building metal-organic complexes based on 1,2,4,5 - benzenetetracarboxylic acid.docx

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基于1,2,4,5-苯四甲酸构筑金属有机配合物-building metal-organic complexes based on 1,2,4,5 - benzenetetracarboxylic acid

Themetal-organiccomplexesconstructedby1,2,4,5-BenzenetetracarboxylicAcidAbstractCarboxylicacidLigandshavebeenwidelystudiedbecauseoftheirstrongcoordin-ationabilityandvarietiesofcoordinationmodes.Asisknown,theligandconformati-on,coordinationgeometriesofthemetalion,thecoordinationenvironmentofmetalio-nandaddingauxiliaryligandhavesignifinantinfluenceonthefinalstructuresofthecoordinationcomplexes.So,inthispaper,wehaveconstructedninemetal-organiccomplexeswithH4BTAandmetalions.Thedetailedcontentsofthethesisareasfollows:Threemetal-organiccomplexes[Ni(H2O)4(bipy)](BTA)0.5·H2O(1)、[Co(H2O)4(bipy)](BTA)0.5·H2O(2)、[Ni(H2O)6]2(BTA0.5)4(3)wereobtainedunderroomtemperaturewithH4BTAasatemplatingagent.Fourtransitionmetal-organiccomplexes,[Zn(H2O)(bipy)0.5(BTA)0.5]·H2O(4)、[Co2(H2O)6(phen)2(BTA)]·H2O]n(5)、[Co(Im)2(H4BTA)0.5]n(6)、[Cd(H2O)4(bipy)0.5(BTA)]n(7)withH4BTAandauxiliaryligandsunderhydrothermalconditionshavebeensynthesized.Twometal-organiccomplexes,[Gd2(H4BTA)1.5(H2O)8]·(H2O)4(8)、[Tm2(H4BTA)1.5(H2O)5]·(H2O)3(9)basedonH4BTAandLanthanidemetalunderhydrothermalconditionshavebeensynthesized.Allcomplexeshavebeendeterminedbysingle-crystalX-raydiffraction.1、2and3belongtosupramolecularcomplexes.inaddition,complexe1and2areisostructural,PXRDconfirmedthattheBTA4-ionsactasthetemplatedmoleculesforsupportingthethreedimensionalstructure;complexe4istwo-dimensionalgrid-likelayer;complexe5istwo-dimensionalstructure;complexe6istwo-dimensionalinterpenetratedstructure;complexe7isone-dimensionalchains.Furthermore,the3Dsupramolecularstructureofthecomplexe1-7areconstructedbyintermolecularH-bondingorπ-πinteractions.Complexe8and9are3Dporousmetal-organicframeworks.Thethermogravimetricanalysis、elementalanalysis,Infraredspectraofthesecomplexewasdiscussedandthethermogravimetricanalysisexhibitedhighstabilityanalyzed．Keywords:Metal-organiccoordinationcomplexe,H-bonding,π-πinteractions,1,2,4,5-BenzenetetracarboxylicAcid.目录第一章绪论1.1概述··················································································