混合型水性无机富锌涂料的制备及其性能分析-preparation and performance analysis of mixed waterborne inorganic zinc-rich coatings.docx

混合型水性无机富锌涂料的制备及其性能研究摘要随着石油战略储备建设的进行，人们对石油储罐的需求也越来越大。由于储 罐的钢材结构与储罐所在地区的环境因素，储罐很容易受到腐蚀，因此，储罐表 面防腐涂层的制备也成为一项重要课题。富锌涂料中的颜填料有片状锌粉和球状 锌粉，片状锌粉同球状锌粉相比，片状富锌涂料具有优良的屏蔽效果，良好的电 化学保护作用、优异的沉淀性以及用量只有球状锌粉的三分之一等特点，在近年 来被广泛研究。水性无机富锌涂料具有零 VOC 排量，是一种环境友好型涂料。科学家也在 片状富锌涂料上投入了大量精力，但是片状锌粉相比球状锌粉也存在一定的不足 之处，如，干燥所需时间较长、电化学极化率大等。所以，通过向片状锌粉中加 入一定比例的球状锌粉制得的混合型水性无机富锌涂料对石油储罐等钢制材料 的防腐具有重大意义。本文首先研究了不同公司生产的硅溶胶以及不同助剂对制备模数比为 5：1 的硅酸钾的影响，并同时探讨了助剂种类、温度，溶液 pH，搅拌速度、甲基三 甲氧基硅烷的用量等因素对试验的影响，最终确定制备乙组分的最优条件为温度 50℃，转数 3500rpm、溶液 pH 控制在 11.0，其助剂为 6%甲基三甲氧基硅烷。其次将制得的高模数硅酸钾溶液与片状锌粉混合制得片状无机富锌涂料，再 向该涂料中加入一定比例的球状锌粉，得到混合型水性无机富锌涂料。探究不同 锌粉含量下富锌涂料的成膜属性，成膜时间以及涂层的耐腐蚀性能。证明了在片 状锌粉中加入球状锌粉后，涂料的性能更优异。然后通过常规性测试，盐雾性实验，耐酸碱性、耐盐水性、耐水性、耐热性、 耐有机溶剂性等实验对混合型水性无机富锌涂料涂膜进行性能研究。最终确定性 能优异的混合型水性无机富锌涂料的锌粉比例为片状锌粉 40%，球状锌粉 10%。关键词：战略储备、水性无机富锌涂料、硅酸钾溶液、球状锌粉、片状锌粉STUDY ON PREPARATION AND PROPERTIES OF HYBRIDWATER-BORNE INORGANIC ZINC-RICH COATINGAbstractWith the conduct of thestrategic petroleum reserve construction，we need more oil storage tanks. Due to the tank of steel structure and tank area environment factors, tank is very vulnerable to corrosion,so，tank surface anti-corrosion coating preparation has become an important topic. The zinc coating pigment involve flake zinc powder and ball zinc powder，Compared Flake zinc powder with ball zincpowder，Flake zinc coating has excellent shielding effect, good electrochemicalprotection, Excellent settling performance and Only a third of the ball zinc powder dosage, has been widely studied in recent years .Water-borne inorganic zinc-rich coating has zero VOC emissions. It is a kind of environmental friendly coatings. Scientist Put in a great deal of energy on Flake zinc coating. But compared flake zinc powder with ball zinc powder,f lake zinc powder has some shortcomings, Such as, dry for a longer period oftime, electrochemical polarization rate big, etc.so, It hasgreat significance for oil tank steel material corrosion that Preparation of hybrid water-borne inorg