核壳均具有树枝状结构新型共聚物制备及应用-preparation and application of novel copolymer with dendritic core-shell structure.docx
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核壳均具有树枝状结构新型共聚物制备及应用-preparation and application of novel copolymer with dendritic core-shell structure
complexeswithhydrophilicHPEIascoreandhydrophobicD1-C16,D1-C8orD2-C16asshell.Thesesupramolecularcomplexescouldbeusedasnanocarrierstoefficientlyaccommodatethehydrophilicanionicguests.Comparedwiththecorrespondingnanocarrierswithlinearshell,thosewithdendriticshellshowedbigadvantages,suchashigherencapsulationcapacity,betterresistancetotheemulsion,highencapsulationcapacityusingalessamountofpolymerandlesshydrophobicchains.5.Aseriesofnovelwater-solublehyperbranchedcopolymerswerepreparedthroughtheanionicring-openingpolymerizationofglycidolusingdifferentmolecular-weightHPEIasthemacroinitiator.Thepolymerizationconditionandpurificationmethodwereoptimized.Furthermore,thesenovelamphiphilichyperbranchedcopolymerscouldbeusedastemplateandstabilizertopreparewater-solubleAuNPs.KEYWORDS:Hyperbranchedpolyethylenimine,Goldnanoparticle,Encapsulation,Supramolecualrcomplex,catalysis目录第一章绪论.....................................................11.1概述...........................................................11.2树枝形聚合物...................................................21.2.1树枝形聚合物概念............................................21.2.2树枝形聚合物组成、结构特征及合成............................31.3树枝形聚合物的功能化及应用.....................................51.3.1树枝形聚合物的功能化........................................51.3.2树枝形聚合物在包裹客体分子方面的应用........................61.3.3树枝形聚合物在分子自组装方面的应用.........................131.3.4树枝形聚合物在膜材料中的应用...............................161.3.5树枝形聚合物在聚合物共混中的应用...........................171.3.6树枝形聚合物在聚电解质中的应用.............................171.3.7树枝形聚合物在医用生物材料中的应用.........................181.3.8树枝形聚合物在其他领域中的应用.............................191.4树枝状共聚物的研究进展........................................19第二章新型油溶两亲性超支化共聚物的制备及客体包裹性能............252.1引言..........................................................252.2实验部分......................................................252.2.1实验试剂...................................................252.2.2实验仪器...................................................272.2.3主要缩写说明................
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