尖晶石型锂离子筛制备方法及lih交换性能分析-preparation method of spinel lithium ion sieve and analysis of lih exchange performance.docxVIP

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尖晶石型锂离子筛制备方法及lih交换性能分析-preparation method of spinel lithium ion sieve and analysis of lih exchange performance.docx

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尖晶石型锂离子筛制备方法及lih交换性能分析-preparation method of spinel lithium ion sieve and analysis of lih exchange performance

AbstractIonexchangetechniqueisconsideredasthebestpromisingwayofbeneficiateLi+fromsaltlakebrineorseawater,andspinelLiMn2O4oritsdopingcompoundiscommonlyconsideredasakindofideallithiumionsieveprecursormaterialandhasbeenresearchedbyscientistformanyyearsindifferentcountries.Thefirstpartofthisessayistheforeword,mainlyincludestheintroductionofthetheprojectbackground、reviewoftheliteraturesandthesummaryofworkofthewholeessay.ThesecondpartisaboutthepreparingoftheLiMn2O4microsphereswithholesandthestudyingofitsionexchangeproperties.Weprepared500mLMnSO4solutionwiththemoleconcentrationof0.03000mol/Landthenadded100mLabsoluteethylalcohol,andthenadded500mL0.3000mol/LNH4HCO3solutionslowlyattheconditionofmagneticstirring,andthenletstandfor2–3h,discardedsupernatantandthenfilteredit,thendriedthefilterresidue,wegotMnCO3microsphere.ThenweheatedtheMnCO3microspheresampleat350oCfor4h,waiteduntilthesampleturnsascoldastheenvironmentandthendippeditinto0.1mol/Lhydrochloricacid,waiteduntilnobubbleappears.Thenfiltereditanddriedthefilterresidue,thedriedfilterresiduewasthesampleofMnO2microspheres.ThenwedippedtheMnO2microsphereintoLiOHsolutionandevaporatedwaterattemperature80oC,heatedthemixtureat700oCfor10hforpreparingLiMn2O4microsphereswithholes.TherateofthelostsofLi+andthedissolutionofMnin(NH4)2S2O8solutionwithdifferenttemperatureswasstudied,andtheresultshowedthat90oCwasthebesttemperatureforincreasingtheextractionrateofLi+andreducingthedissolutionofMn.H-Mn-OsampleswasgotaftertheLiMn2O4samplewasdippedin0.5mol/Lof(NH4)2S2O8solutionwitht=90oCfor1h,andthemeasurementresultofXRDandSEMofthesampleH-Mn-OshowedthatitscrystallinephaseandappearancenearlyremainthesamewithLiMn2O4.Westudiedhowthedippingtime、thebasicityofsolutionandthetemperatureinfluencedtheadsorptionpropertiesofH-Mn-O,andtheresultshowedthatH-Mn-OcouldreachthebalanceoftheLi+adsorption(3.04mmol/g)afterdippinginpH=10LiClsolutionfor12h.ThemeasurementoftheadsorptiveselectivityshowedthatH-Mn-OhashighadsorptiveselectivitytoLi+.Thethirdpartisabouttheprep