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碱性溶液中砷萃取分离分析-extraction and separation analysis of arsenic in alkaline solution
85.3% of AsIII can be extracted with single stage extraction. The AsIIIconcentration of the rafinate can be lowered down to less than 1.34×10-3 mol/L and the extraction can be achieved as more than 98.5% through 4 stages counter current extraction, so that arsenic can be effectively removed from the alkaline solutions. The loaded organic can be effectively stripped by 1.0 mol/L NaCl+2.0 mol/L NaOH mixed solutions and the single-stage stripping rate is achieved as 89.82%. Through six-stage counter current stripping, the idea stripping rate can be achieved as more than 98% with the phase ratio of O/A=2:1. The organic structure change during the modification, extraction and stripping is further analyzed on the basis of IR.Key Words: Alkaline solution; arsenic; solvent extraction; separation目录摘要.........................................................................................................................IAbstract..........................................................................................................................II第一章 绪论.............................................................................................................. 11.1 选题的目的及研究意义................................................................................. 11.2 砷及含砷物料的研究现状............................................................................. 21.2.1 砷的理化性质及其资源...................................................................... 21.2.2 铜冶炼过程中砷的分布概况.............................................................. 41.2.3 高砷烟灰处理工艺进展...................................................................... 51.2.4 砷溶剂萃取的研究现状...................................................................... 81.3 课题的研究内容、研究目标....................................................................... 101.4 课题拟解决的关键问题及创新之处........................................................... 121.4.1 关键问题及关键技术........................................................................ 121.4.2 创新之处........
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