抗黄变热塑性聚氨酯胶粘剂的制备与性能分析-preparation and performance analysis of anti-yellowing thermoplastic polyurethane adhesive.docx

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2018-05-29 发布于上海
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抗黄变热塑性聚氨酯胶粘剂的制备与性能分析-preparation and performance analysis of anti-yellowing thermoplastic polyurethane adhesive.docx

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抗黄变热塑性聚氨酯胶粘剂的制备与性能分析-preparation and performance analysis of anti-yellowing thermoplastic polyurethane adhesive

摘要simultaneouslyaddedtotheTPUbycompositeageing-resistantagents,theanti-agingpropertiesofTPUweresignificantlyimprovedbythehelpofassociativeeffectamongtheabovethreeageing-resistentagents.TheoptimalmassratioamongUV-329,UV-622and1010,was3:3:2.thetotalamountofcompositeageing-resistantagentswas1.7%onthebasisofPBA3000.Theresultsshowedthat,althoughthepropertiesofTPUcontainingcompositeageing-resistantagentswereslightlylowerthanthoseofTPUno-containingcompositeageing-resistantagents,thepropertiesofthelatterdeclinedmoreobviouslythanthoseoftheformerinthelightofUVfor150h.Thepropertychangesofthelatterwereasfollows:tensilestrengthdeclined44%,elongationatbreakdeclined66%andadhesivestrengthdeclined25%.However,thepropertychangesoftheformerwereasfollows:tensilestrengthdeclined10%,elongationatbreakdeclined26%andadhesivestrengthdeclined9.5%.Inaddtion,theyellowinggradeofTPUcontainingcompositeageing-resistantagentscouldreach4.1inthelightofUVfor8h.Dibutyltindilaurate(DBTDL)asacatalystintheproductionofTPUisharmfultohumanhealth,soTPUcontainingDBTDLisnotsuitableforfood,medicine,etal.Inthispaper,synthesisofbismuthlaurateasanon-toxiccatalystanditsapplicationintheproductionofTPUwerealsostudied.At90~95℃,sodiumlauratewasfirstsynthesizedbythesaponificationbetweenlauricacidandsodiumhydroxide,thenbismuthlauratewasobtainedbythedoubledecompositionreactionbetweensodiumlaurateandbismuthnitrate.Whentheadditionamountofbismuthlauratewas0.04%onthebasisofPBA3000,reactiontimeofTPUwasshortenedfrom4minto2min,sobismuthlauratehadsignificantlycatalyticactivityfor–NCO/-OHreactionandimprovedthepropertiesofTPUtosomeextent.KEYWORDS:Ageing-resistantagents,Thermoplasticpolyurethaneadhesive,Synthesis,Property,BismuthlaurateDissertationType:AppliedBasicResearchIV缩略语词汇表缩略语词汇表符号名称TPU热塑性聚氨酯PBA聚己二酸丁二醇酯BDO1,4-丁二醇MDI二苯基甲烷二异氰酸酯UVA紫外线吸收剂HALS受阻胺光稳定剂FTIR红外光谱XRDX射线衍射60第1章绪论第1章绪论1.1热塑性聚氨酯胶粘剂聚氨酯（Polyurethane：PU）是一种分子主链上含有氨基甲酸酯（-NH-COO-）基团的高分子加成聚合物[1]。聚氨酯合成时原料不同、工艺不同，可以制备出性能各异、满足不同需求的聚氨酯产品，如泡沫、弹性体、纤维、涂料、胶粘剂等，广泛应用于交通运输、建筑工程、服装、机电设备、航空航天、医