硼对有序态Ni_Fe合金氢气环境中氢脆敏感性的影响.docVIP

——————————————————————————————————————————————— 硼对有序态Ni_3Fe合金氢气环境中氢脆敏感性的影响 第45卷　第2期Vol.45,No.2 JOURNALOFNANJINGUNIVERSITY 　2009年3月Mar.ω2009(NATURALSCIENCES) 先进材料测试及表征专栏南京大学学报(自然科学) 硼对有序态Ni3Fe合金氢气环境中 氢脆敏感性的影响3 马　杰1,陈业新1,LiuCT2 (1.上海大学材料研究所,上海,200072; 2.田纳西大学材料科学与工程系,美国,TN37996-2200)33 摘　要:　硼含量(0101～0106wt.%B)对有序态Ni224at.%Fe较大的影响,对有序态Ni3Fe.有序Ni3Fe合金的晶粒尺寸得到细化,材料的强韧性提高;气环境中的氢脆.当合金中硼含量为0106wt.%时,有序态3(IH2为 1%,与无硼Ni3Fe合金相比,,无硼有序态Ni3Fe;3,合金断口形貌中的沿晶断;01%后,断口形貌变为全部塑性的韧窝状断口.合3Fe合金中的硼提高了合金的晶界强度.硼对有序态Ni3Fe合金在氢,硼对有序态Ni3Fe合金中由氢气诱发的环境氢脆有较强的抑制作用. 关键词:　Ni3Fe金属间化合物,环境氢脆,硼含量 中图分类号:　TG172,TG14611 Effectofboronontheenvironmentalembrittlementof orderedNi3Fealloysingaseoushydrogen MaJe,ChenYe2Xin,LiuCT112 (1.InstituteofMaterialsScience,ShanghaiUniversity,Shanghai,200072,China; 2.DepartmentofMaterialsScienceandEngineering,UniversityofTennessee,TN37996-2200,USA)Abstract:　InthispaperthetensilepropertiesofanorderedNi224at.%Fealloysdopingwithvariousboroncontent(0101～0106wt.%)whentestedinvacuumandingaseoushydrogenhavebeeninvestigated.Theresultsshowthatthegrainsarerefined,ductilityandstrengthareincreased,andtheH22inducedembrittlementofthealloyingaseoushydrogenissuppressedsubstantiallywhenboronisdopedinNi224at.%Fealloys.Thehydrogenembrittlementfac2tor(IH2)oftheorderedNi3Fealloydecreasessharplywiththeincrementofboroncontentinthealloy.IH2oftheorderedNi3Fealloydecreaseslinearlywhenboroncontentincreasesfrom0to0103wt.%,thentherateslowswhen3基金项目:国家自然科学基金50671057) 收稿日期:2008-10-00 33通讯联系人,E2mail:yxchen@ ?242? 南京大学学报(自然科学) 　　第45卷 boroncontentincreasescontinuously.ComparedwithB2freeNi3Fealloy,IH2oftheorderedNi3Fedopingwith0106wt.%Bdecreasesby9817%.Theboron2freeorderedNi3Fedisplaysthebrittlefracture(intergranularfrac2ture)whentestedingaseousH2.Thepartsofdimplerupture(transgranularfracture)inthefractographincreasegraduallywithincreasingtheconcentrationofboroninthealloywhentensiletestswereconductedingaseou