年产万吨二甲醚的精馏系统及二甲醚精馏塔设计.docVIP

摘要作为LPG?和石油类的?替代燃料，目前二甲醚?(DME)倍受注目。DME是具?有与LPG?的物理性质?相类似的化?学品，在燃烧时不?会产生破坏?环境的气体?，能便宜而大?量地生产。与甲烷一样?，被期望成为?21世纪的?能源之一。目前生产的?二甲醚基本?上由甲醇脱?水制得，即先合成甲?醇，然后经甲醇?脱水制成二?甲醚。甲醇脱水制?二甲醚分为?液相法和气?相法两种工?艺，本设计采用?气相法制备?二甲醚工艺?。将甲醇加热?蒸发，甲醇蒸气通?过γ-AL2O3?催化剂床层?,气相甲醇脱?水制得二甲?醚。气相法的工?艺过程主要?由甲醇加热?、蒸发、甲醇脱水、二甲醚冷凝?及精馏等组?成。主要完成以?下工作： 全过程的物?料及能量衡?算； 通过对AS?PENPL?US的学习?对精馏系统?进行模拟； 3）二甲醚精馏?塔的选型设?计计算； 4）二甲醚精馏?塔选型的校?核； 5）通过对塔的?设计计算，利用CAD?绘制出PI?D图、PFD图、设备图以及?车间布置图?。 关键词二甲醚，甲醇，工艺设计，二甲醚精馏?精馏塔设计? Abstr?act As LPG and oil alter?nativ?e fuel, DME has drawn? atten?tions? at prese?nt. Physi?cal prope?rties? of DME is simil?ar for LPG, and don’t produ?ce combu?stion? gas to damag?e the envir?onmen?t, so, It can be produ?ced large?ly. Like metha?ne, DME is expec?ted to becom?e 21st centu?ry energ?y sourc?es., DME is prepa?red by metha?nol dehyd?ratio?n, namel?y, synth?etic metha?nol first? and then metha?nol dehyd?ratio?n to dimet?hyl ether?by metha?nol dehyd?ratio?n. Metha?nol dehyd?ratio?n to DME is divid?ed into two kinds? of liqui?d phase? and gas-phase? proce?ss. This desig?n uses a proce?ss gas of dimet?hyl ether? prepa?red by dimet?hyl. Heati?ng metha?nol to evapo?ratio?n, metha?nol vapor? throu?gh the γ-AL 2O3 catal?yst bed, vapor? metha?nol dehyd?ratio?n to dimet?hyl ether?by. ?This proce?ss is made of metha?nol proce?ss heati?ng, evapo?ratio?n, dehyd?ratio?n of metha?nol, dimet?hyl ether? conde?nsati?on and disti?llati?on etc. Compl?eted for the follo?wing work: The whole? proce?ss of the mater?ial and energ?y balan?ce calcu?latio?n; The disti?llati?on syste?m is simul?ated throu?gh the study? of ASPEN?PLUS 3) Calcu?latio?n and selec?tion of desig?n DME disti?llati?on colum?n; 4) Check? selec?tion DME disti?llati?on colum?n; 5) Throu?gh the calcu?latio?n of desig?n of the tower?, using? CAD to draw PID chart?, PFD chart?, equip?ment and works?hop layou?t. Key words?: DME, metha?nol, Proce?ss Desig?n, Desig?n of DME fract?ionat?ing tower? 目录 第1章 文献综述 1 1.1 二甲醚的现?状 1 1.1.1 甲醚的市场?分