锂离子电池性能衰减机理以及改进方法研究.pptxVIP

锂离子电池性能衰减的机理以及改进方法的研究Study on mechanism and improvement of the performance fading of Lithium ion batteries;Outlines;Lithium ion battery - How it works;Lithium Ion Batteries;Cathodes Anodes;LiMn2O4/Graphite Lithium ion batteries;Capacity fading mechanism of LMO/C system;Dissolution of Mn- Loss of active LiMn2O4;Dissolution of Mn- formation of inactive Mn(IV);Existence of Mn on aged anode;Oxidation state of Mn on aged anode;Correlation between Mn dissolution-deposition and performance fade ;Suppression the dissolution - deposition;Improve the cycle performance ;Surface coating- Improve cycle performance but form physical barrier;Cationic doping – with active metal ions;Cationic doping – with inactive metal ions;Electrolyte additives-Scavenge H2O or HF;Electrolyte additive-complex with Mn2+;Electrolyte additives – Modify the surface of anode;Challenges for Mn DMD process;Challenges for improving the cycle performance;Objectives of my work;Outlines;LiMn2O4 nanoparticles synthesized by solid state method;8/1/2016;Morphology of electrode materials;Mn deposited on anodes;Half cells-LiMn2O4 vs. Li anode;Full cells-LiMn2O4 vs. Different anodes;XAFS ;X-ray Absorption Spectrum (XAS) on Anodes (XANES);EXAFS SPECTROSCOPY;X-ray Absorption Spectrum (XAS) on Anodes (EXAFS);X-ray Photoelectron Spectrum on anodes (XPS);Additional X-ray Photoelectron Spectrum;Mn deposition reaction;SEI layer stored in Mn2+;Ion-exchange and Impedance rising;Impedance Measurements on Carbon Anode;Mn deposition reaction on graphite;Summary;Outlines;Surface doping;TiO2-coated and Ti-surficial doped LiMn2O4;Morphology of the surface modified LiMn2O4 ;Crystal Structure;Surface composition by XPS;Charge-Discharge behavior;Cycle performance;Mn dissolution- deposition;Impedance comparison;Full cell test;Summary;Outlines;Commonly used electrolyte additives;Cycle performance @ 55oC;8/1/2016;Mn deposition on MCMB after cycling(ICP-AAS);Ion-exchange reaction between Mn2+ and SEI;In-situ XRD of the VO2 coa