钢混结构腐蚀监测用全固态参比电极的eb-pvd制备与性能表征-preparation and characterization of all-solid reference electrode for corrosion monitoring of steel-concrete structures by e b - pvd.docxVIP

AbstractCorrosion of reinforcing steel is one of the main factors, which cause the durability degeneration of reinforced concrete structures and bring huge economic losses. Corrosion monitoring of reinforcing steel provides the scientific basis for corrosion protection, security assessment and the whole life design of reinforced concrete structures. Corrosion monitoring sensors are the carrier and platform for the realization of steel corrosion monitoring. The reference electrode is the core component of electrochemical corrosion monitoring sensors. The development of all solid-state reference electrode (ASSRE) with excellent service performance is a key scientific issue for implementing the corrosion monitoring sensor system of reinforced concrete structures. In this paper, binary alloy functional cores with excellent service performance are developed by using the advanced membrane technology-electron beam physical vapor deposition (EB-PVD). The alloy films of the functional cores are systematically microcosmically characterized and analyzed. The response of the ASSRE integrated with the developed alloy thin films is tested in typical service environment. Finally, the ASSRE is integrated into a series of corrosion sensors to monitor the corrosion of reinforced concrete slabs. This paper aims to provide core components for the corrosion sensors used in structural health monitoring and lay the foundation for the large-scale and integrated production of corrosion sensors. Main contents of this paper are as follows:Combined with the specific requirements on functional cores of ASSRE,the specific preparation process of the binary alloy thin films by using EB-PVD technology is determined. The preparation process of the conductive layer and the process conditions of the heat treatment and postoxidation of the prepared alloy films are definitized. A micro-analysis method for the binary alloy film and a performance testing method for the ASSRE are proposed, respectively.T