刚性 多连接的金属-有机配位网络的构筑和性质分析-construction and property analysis of rigid multi-connected metal-organic coordination network.docxVIP

AbstractMetal-organic frameworks (MOFs) are constructed as a new type of porous materials due to their high specific surface area, versatile structures, easily controlled porous channels, multiple functions. This kind of materials exhibit potential application both in scientific research and industry, especially in the application of gas storage, luminescence materials, magnetic behaviors, asymmetric catalysis, non-linear optics, etc. In recent years, designing new types of ligands and constructing multifunctional metal-organic frameworks have become a hot topic in the field of inorganic chemistry. Using rigid and multi-carboxylate ligands especially some large ones to construct metal-organic frameworks can greatly enhance its thermal stability and scale of cavities. Besides, some of the ligands will bring varieties of excellent properties to the new materials.In this thesis, two rigid ligands: 3, 5-bis(3,5-dicarboxylphenylethynyl)-pyridine (L1) and 9, 10-bis (4-carboxylpenylethynyl) anthracene (L2) have been synthesized and characterized by 1H-NMR and IR. Using these two ligands, three coordination compounds (1, 2, 3) have been constructed and characterized by X-ray diffraction analysis. The obtained results show that framework 1 {[Cu24L112(H2O)12]·180H2O·12DMF} crystallizes in cubic space group Im3m, and the asymmetric unit consists of two crystallographically quarter copper ions, and axial position is coordinated by pyridyl N atom with Cu-N distance 2.132(8) ?. In this framework, three types of pores are generated with the Cu ions and bridging ligands, then 3,5-bis(3,5-dicarboxyl phenyl-ethynyl)-pyridine(L)coordinate to Cu(II) ions to form metal-organic cuboctahedrons (MOCs), but one type of the pores is occupied by MOC unit to create a self-interpenetrated framework.According to the absorption and thermal analysis, the observed results indicate that such a three-dimensional metal-organic framework with high connection exhibits good gas absorption capabilit